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Name	L-Glutamyl-4-nitroanilide	EINECS	230-748-5
CAS No.	7300-59-6	Density	1.463 g/cm³
PSA	138.24000	LogP	2.02190
Solubility	N/A	Melting Point	185-188°C
Formula	C₁₁H₁₃N₃O₅	Boiling Point	590.6 °C at 760 mmHg
Molecular Weight	267.241	Flash Point	311 °C
Transport Information	N/A	Appearance	cream coloured to light yellow powder
Safety	22-24/25	Risk Codes	N/A
Molecular Structure		Hazard Symbols	N/A
Synonyms	Glutaranilicacid, 2-amino-4'-nitro-, L- (8CI);L-Glutamic acid g-p-nitroanilide;L-Glutamyl-4-nitroanilide;L-g-Glutamyl-p-nitroanilide;g-Glutamyl-p-nitroanilide;g-L-Glu-p-nitroanilide;g-L-Glutamyl-p-nitroanilide;	Article Data	4

L-Glutamyl-4-nitroanilide Synthetic route

: 113277-32-0
(S)-2-Benzyloxycarbonylamino-4-(4-nitro-phenylcarbamoyl)-butyric acid

: 7300-59-6
L-glutamic acid 5-(4-nitroanilide)

Conditions

Conditions	Yield
With hydrogen; palladium on activated charcoal In methanol

: 848215-13-4
(S)-4-[2-(4-Nitro-phenylcarbamoyl)-ethyl]-5-oxo-oxazolidine-3-carboxylic acid benzyl ester

: 7300-59-6
L-glutamic acid 5-(4-nitroanilide)

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: lithium hydroxide / tetrahydrofuran; H2O / 0.5 h / 5 °C 2: hydrogen / Pd/C / methanol View Scheme

: 56-86-0
L-glutamic acid

: 7300-59-6
L-glutamic acid 5-(4-nitroanilide)

Conditions

Conditions	Yield
Multi-step reaction with 6 steps 1: 98 percent / triethylamine / methanol / 3 h 2: 90 percent / toluenesulfonic acid / toluene / 3 h / Heating 3: thionyl chloride / CH2Cl2 / 0.5 h / Heating 4: pyridine / CH2Cl2 / 0.25 h / 20 °C 5: lithium hydroxide / tetrahydrofuran; H2O / 0.5 h / 5 °C 6: hydrogen / Pd/C / methanol View Scheme

: 1155-62-0
N-benzyloxycarbonyl-L-glutamic acid

: 7300-59-6
L-glutamic acid 5-(4-nitroanilide)

Conditions

Conditions	Yield
Multi-step reaction with 5 steps 1: 90 percent / toluenesulfonic acid / toluene / 3 h / Heating 2: thionyl chloride / CH2Cl2 / 0.5 h / Heating 3: pyridine / CH2Cl2 / 0.25 h / 20 °C 4: lithium hydroxide / tetrahydrofuran; H2O / 0.5 h / 5 °C 5: hydrogen / Pd/C / methanol View Scheme

: 58456-26-1
(S)-4-<2'-(Chloroformyl)ethyl>-5-oxooxazolidin-3-carbonsaeure-benzylester

: 7300-59-6
L-glutamic acid 5-(4-nitroanilide)

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: pyridine / CH2Cl2 / 0.25 h / 20 °C 2: lithium hydroxide / tetrahydrofuran; H2O / 0.5 h / 5 °C 3: hydrogen / Pd/C / methanol View Scheme

: 23632-67-9
(S)-3-[3-(benzyloxycarbonyl)-5-oxooxazolidin-4-yl]propanoic acid

: 7300-59-6
L-glutamic acid 5-(4-nitroanilide)

Conditions

Conditions	Yield
Multi-step reaction with 4 steps 1: thionyl chloride / CH2Cl2 / 0.5 h / Heating 2: pyridine / CH2Cl2 / 0.25 h / 20 °C 3: lithium hydroxide / tetrahydrofuran; H2O / 0.5 h / 5 °C 4: hydrogen / Pd/C / methanol View Scheme

: 24277-39-2
N-tert-butoxycarbonyl glutamic acid tert-butyl ester

: 100-01-6
4-nitro-aniline

: 7300-59-6
L-glutamic acid 5-(4-nitroanilide)

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: HATU; N-ethyl-N,N-diisopropylamine / N,N-dimethyl-formamide / 0.5 h / 120 °C / Microwave irradiation 2: hydrogenchloride / 1,4-dioxane / 4 h / 40 °C View Scheme

: C20H29N3O7

: 7300-59-6
L-glutamic acid 5-(4-nitroanilide)

Conditions

Conditions	Yield
With hydrogenchloride In 1,4-dioxane at 40℃; for 4h;

: 7300-59-6
L-glutamic acid 5-(4-nitroanilide)

: 100-01-6
4-nitro-aniline

Conditions

Conditions	Yield
at 37℃; 0.1 M Tris-HCl buffer, γ-glutamyltransferase from mushroom Lentinus edodes; other enzyme; Michaelis constant Km and Vmax determination;
With religiosin B at 37℃; pH=8; Kinetics; aq. buffer; Enzymatic reaction;
With religiosin C at 37℃; pH=8; Kinetics; Concentration; aq. buffer; Enzymatic reaction;

: 556-50-3
glycylglycine

: 7300-59-6
L-glutamic acid 5-(4-nitroanilide)

: 6706-20-3
L-α-glutamyl=>glycyl=>glycine

Conditions

Conditions	Yield
With HCl buffer; rat kidney γ-glutamyltranspeptidase pH=8.0; Enzyme kinetics;

L-Glutamyl-4-nitroanilide Specification

The L-Glutamine,N-(4-nitrophenyl)-, with the CAS registry number 7300-59-6, is also known as (S)-2-Amino-5-((4-nitrophenyl)amino)-5-oxopentanoic acid. Its EINECS number is 230-748-5. This chemical's molecular formula is C₁₁H₁₃N₃O₅ and molecular weight is 267.24. What's more, its systematic name is N-(4-nitrophenyl)-L-glutamine. It should be sealed and stored in a cool and dry place at the temperature of 2-8 °C.

Physical properties of L-Glutamine,N-(4-nitrophenyl)- are: (1)ACD/LogP: 1.29; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -1.21; (4)ACD/LogD (pH 7.4): -1.22; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 1; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 8; (10)#H bond donors: 4; (11)#Freely Rotating Bonds: 7; (12)Polar Surface Area: 95.67 Å²; (13)Index of Refraction: 1.643; (14)Molar Refractivity: 66.02 cm³; (15)Molar Volume: 182.5 cm³; (16)Polarizability: 26.17×10^-24 cm³; (17)Surface Tension: 73.2 dyne/cm; (18)Density: 1.463 g/cm³; (19)Flash Point: 311 °C; (20)Enthalpy of Vaporization: 92.67 kJ/mol; (21)Boiling Point: 590.6 °C at 760 mmHg; (22)Vapour Pressure: 8.57E-15 mmHg at 25°C.

When you are using this chemical, please be cautious about it as the following:
You should not breathe dust, and you also should avoid contact with skin.

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: O=C(Nc1ccc(cc1)[N+]([O-])=O)CC[C@@H](C(=O)O)N
(2)InChI: InChI=1/C11H13N3O5/c12-9(11(16)17)5-6-10(15)13-7-1-3-8(4-2-7)14(18)19/h1-4,9H,5-6,12H2,(H,13,15)(H,16,17)/t9-/m0/s1
(3)InChIKey: WMZTYIRRBCGARG-VIFPVBQEBD

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