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Cas Database

Name	L-Proline, glycyl-	EINECS	211-880-2
CAS No.	704-15-4	Density	1.356 g/cm³
PSA	83.63000	LogP	-0.34110
Solubility	very faint turbidity	Melting Point	185℃
Formula	C₇H₁₂N₂O₃	Boiling Point	411.3 °C at 760 mmHg
Molecular Weight	172.184	Flash Point	202.6 °C
Transport Information	N/A	Appearance	WHITE POWDER
Safety	26	Risk Codes	36
Molecular Structure		Hazard Symbols	Xi
Synonyms	L-Proline,1-glycyl-;Proline, 1-glycyl-, L- (6CI,8CI);(S)-1-(2-Aminoacetyl)pyrrolidine-2-carboxylic acid;1-Glycylproline;7: PN:WO03052099 PAGE: 83 claimed protein;Glycyl-L-proline;N-Glycyl-L-proline;N-Glycylproline;NSC 97929;	Article Data	22

L-Proline, glycyl- Synthetic route

: 23500-10-9
(S)-1-(2-chloroacetyl)pyrrolidine-2-carboxylic acid

: 704-15-4
H-Gly-Pro-OH

Conditions

Conditions	Yield
With ammonium hydroxide

: 1160-54-9
(2S)-1-(2-[[(benzyloxy)carbonyl]amino]acetyl)tetrahydro-1H-pyrrole-2-carboxylic acid

: 704-15-4
H-Gly-Pro-OH

Conditions

Conditions	Yield
With methanol; palladium; acetic acid Hydrogenation;
With hydrogen; palladium on activated charcoal

: 95688-74-7
1-(bromoacetyl)-L-proline

: 704-15-4
H-Gly-Pro-OH

Conditions

Conditions	Yield
With ammonium hydroxide

: 1-iodoacetyl-L-proline

: 704-15-4
H-Gly-Pro-OH

Conditions

Conditions	Yield
With ammonium hydroxide

: 56-41-7
L-alanin

: 60189-43-7
H-Gly-Pro-pNA

A: 100-01-6
4-nitro-aniline

B: 837-83-2
gly-pro-ala

C: 704-15-4
H-Gly-Pro-OH

Conditions

Conditions	Yield
With dipeptidyl peptidase IV In glycerol at 40℃;
With dipeptidyl peptidase IV In glycerol at 40℃; Rate constant; Kinetics; constant of partition;

: 60-18-4
L-tyrosine

: 60189-43-7
H-Gly-Pro-pNA

A: 22028-91-7
Gly-Pro-Tyr

B: 100-01-6
4-nitro-aniline

C: 704-15-4
H-Gly-Pro-OH

Conditions

Conditions	Yield
With dipeptidyl peptidase IV In glycerol at 40℃;
With dipeptidyl peptidase IV In glycerol at 40℃; Rate constant; Kinetics; constant of partition;

: 837-83-2
gly-pro-ala

A: 56-41-7
L-alanin

B: 704-15-4
H-Gly-Pro-OH

Conditions

Conditions	Yield
at 37℃; for 0.166667h; 0.1 M Tris HCl buffer pH 8.0, X-prolyl dipeptidyl aminopeptidase from Lactococcus lactis subsp. cremoris nTR;
at 37℃; for 0.166667h; Rate constant; 0.1 M Tris HCl buffer pH 8.0, X-prolyl dipeptidyl aminopeptidase from Lactococcus lactis subsp. cremoris nTR; Km;

: 60189-43-7
H-Gly-Pro-pNA

A: 100-01-6
4-nitro-aniline

B: 704-15-4
H-Gly-Pro-OH

Conditions

Conditions	Yield
at 37℃; for 0.166667h; 0.1 M Tris HCl buffer pH 8.0, X-prolyl dipeptidyl aminopeptidase from Lactococcus lactis subsp. cremoris nTR;
With buffer pH=7.6; dipeptidyl peptidase IV In glycerol at 30℃; Rate constant; Kinetics;
at 37℃; for 0.166667h; Rate constant; 0.1 M Tris HCl buffer pH 8.0, X-prolyl dipeptidyl aminopeptidase from Lactococcus lactis subsp. cremoris nTR; Km, Ki, competitive inhibition by dipeptides;

: 72122-62-4
L-tyrosyl-L-prolyl-L-phenylalanyl-L-prolyl-glycyl-L-prolyl-L-isoleucine

A: 51871-47-7
H-Tyr-Pro-OH

B: 7669-65-0
L-phenylalanyl-L-proline

C: 89187-15-5
Gly-Pro-Ile

D: 704-15-4
H-Gly-Pro-OH

Conditions

Conditions	Yield
at 37℃; for 7h; 0.1 M Tris HCl buffer pH 8.0, X-prolyl dipeptidyl aminopeptidase from Lactococcus lactis subsp. cremoris nTR; Yield given. Yields of byproduct given;

: 72122-62-4
L-tyrosyl-L-prolyl-L-phenylalanyl-L-prolyl-glycyl-L-prolyl-L-isoleucine

A: 51871-47-7
H-Tyr-Pro-OH

B: 7669-65-0
L-phenylalanyl-L-proline

C: 89187-15-5
Gly-Pro-Ile

D: Phe-Pro-Gly-Pro-Ile

E: 704-15-4
H-Gly-Pro-OH

Conditions

Conditions	Yield
at 37℃; Kinetics; 0.1 M Tris HCl buffer pH 8.0, X-prolyl dipeptidyl aminopeptidase from Lactococcus lactis subsp. cremoris nTR;

...Expand

L-Proline, glycyl- Specification

The L-Proline, glycyl-, with CAS registry number 704-15-4, belongs to the following product categories: (1)Pyrrole; (2)Biochemistry; (3)Oligopeptides; (4)Peptide Synthesis; (5)Dipeptides; (6)Dipeptides and Tripeptides; (7)Peptides. It has the systematic name of glycyl-L-proline. This chemical should be stored at the temperature of −20°C.

Physical properties of L-Proline, glycyl-: (1)ACD/LogP: -1.34; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -3.84; (4)ACD/LogD (pH 7.4): -3.94; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 1; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 5; (10)#H bond donors: 3; (11)#Freely Rotating Bonds: 3; (12)Polar Surface Area: 49.85 Å²; (13)Index of Refraction: 1.556; (14)Molar Refractivity: 40.86 cm³; (15)Molar Volume: 126.9 cm³; (16)Polarizability: 16.19×10^-24cm³; (17)Surface Tension: 66.2 dyne/cm; (18)Density: 1.356 g/cm³; (19)Flash Point: 202.6 °C; (20)Enthalpy of Vaporization: 72.82 kJ/mol; (21)Boiling Point: 411.3 °C at 760 mmHg; (22)Vapour Pressure: 6.44E-08 mmHg at 25°C.

You can still convert the following datas into molecular structure:
(1)SMILES: O=C(O)[C@H]1N(C(=O)CN)CCC1
(2)InChI: InChI=1/C7H12N2O3/c8-4-6(10)9-3-1-2-5(9)7(11)12/h5H,1-4,8H2,(H,11,12)/t5-/m0/s1
(3)InChIKey: KZNQNBZMBZJQJO-YFKPBYRVBI
(4)Std. InChI: InChI=1S/C7H12N2O3/c8-4-6(10)9-3-1-2-5(9)7(11)12/h5H,1-4,8H2,(H,11,12)/t5-/m0/s1
(5)Std. InChIKey: KZNQNBZMBZJQJO-YFKPBYRVSA-N

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