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Lead oxide

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Lead oxide

EINECS 215-235-6
CAS No. 1314-41-6 Density 9.1 g/cm3
PSA 36.92000 LogP -1.41600
Solubility Soluble in hydrochloric acid, glacial acetic acid and nitric acid and hydrogen peroxide. Insoluble in water and alcohol. Melting Point 500 ºC
Formula Pb3O4 Boiling Point 800 ºC
Molecular Weight 685.57 Flash Point N/A
Transport Information UN 1479 5.1/PG 2 Appearance red powder
Safety 53-45-60-61 Risk Codes 61-8-20/22-33-50/53-62
Molecular Structure Molecular Structure of 1314-41-6 (Lead oxide) Hazard Symbols OxidizingO,ToxicT,DangerousN
Synonyms

Read lead oxide;Azarcon;C.I. 77578;C.I. Pigment Red 105;Entan;Flowsperse R 12;Gold Satinobre;Heuconin 5;Kremer 42500;Lead orthoplumbate;Lead oxide;Lead oxide (3:4);Lead oxide red;Lead tetraoxide;

 

Lead oxide Chemical Properties

Molecule structure of Lead oxide (CAS NO.1314-41-6):

Molecular Weight: 685.5976 g/mol
Molecular Formula: O4Pb3 
IUPAC Name: 2,4,6,7-Tetraoxa-1λ3,3λ2,5λ3-triplumbabicyclo[3.1.1]heptane 
EINECS: 215-235-6
Product Categories: Inorganics 
Stability: Stable. May react vigorously with reducing agents.
Density: 9.1 g/cm3
Melting Point: 500 °C
Boiling Point: 800°C
Vapor Pressure: 10 mm Hg ( 0 °C)
H-Bond Acceptor: 4 
Exact Mass: 685.907379
MonoIsotopic Mass: 687.909566
Topological Polar Surface Area: 36.9
Heavy Atom Count: 7
Canonical SMILES: O1[Pb]O[Pb]2O[Pb]1O2
InChI: InChI=1S/4O.3Pb
InChIKey: XMFOQHDPRMAJNU-UHFFFAOYSA-N

Lead oxide History

 Lead oxide (CAS NO.1314-41-6) was used as a red pigment in ancient Rome, where it was prepared by calcination of lead white. It was used as a pigment in the production of illuminated manuscripts, and gave its name to the minium or miniature, a style of picture painted with the colour in the ancient and medieval periods. As a finely divided powder, it was also sprinkled on dielectric surfaces to study Lichtenberg figures. It was clearly described by Muhammad ibn Zakarīya Rāzi (Rhazes) in the early 10th century and  was first isolated as a pure compound by Arabic chemists.

Lead oxide Uses

 Lead oxide (CAS NO.1314-41-6) is used in the manufacture of batteries, lead glass and rust-proof primer paints. It finds extensive use as a priming coat for structural steel because it possesses corrosion-inhibiting properties.

Lead oxide Production

 Lead oxide (CAS NO.1314-41-6) is prepared by calcination of lead(II) oxide (also called litharge) in air at about 450 to 480 °C:
6 PbO + O2 → 2 Pb3O4
The resulting material is contaminated with lead(II) oxide. If a pure compound is desired, PbO can be removed by a potassium hydroxide solution:
PbO + KOH + H2O → K[Pb(OH)3] (aq)
Another method of preparation relies on annealing of lead carbonate (cerussite) in air:
6 PbCO3 + O2 → 2 Pb3O4 + 6 CO2
Yet another method is oxidative annealing of lead white:
3 Pb2CO3(OH)2 + O2 → 2 Pb3O4 + 3 CO2 + 3 H2O
In solution, Lead oxide can be prepared eg. by reaction of potassium plumbate with lead acetate:
K2PbO3 + 2 Pb(OCOCH3)2 + H2O → Pb3O4 + 2 KOCOCH3 + 2 CH3COOH
yielding yellow insoluble Lead oxide monohydrate, Pb3O4·H2O, which can be turned into the anhydrous form by gentle heating.

Lead oxide Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
guinea pig LD50 intraperitoneal 220mg/kg (220mg/kg)   "Merck Index; an Encyclopedia of Chemicals, Drugs, and Biologicals", 11th ed., Rahway, NJ 07065, Merck & Co., Inc. 1989Vol. 11, Pg. 854, 1989.
guinea pig LDLo oral 1gm/kg (1000mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

BLOOD: PIGMENTED OR NUCLEATED RED BLLOD CELLS
Archiv fuer Hygiene und Bakteriologie. Vol. 125, Pg. 273, 1941.
mouse LD50 intraperitoneal 17700mg/kg (17700mg/kg)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 26(8), Pg. 51, 1982.
rat LD50 intraperitoneal 630mg/kg (630mg/kg)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 19(3), Pg. 30, 1975.

Lead oxide Consensus Reports

 Lead and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.

Lead oxide Safety Profile

Hazard Codes: OxidizingO, ToxicT, DangerousN
Risk Statements: 61-8-20/22-33-50/53-62 
R61:May cause harm to the unborn child. 
R8 :Contact with combustible material may cause fire. 
R20/22:Harmful by inhalation and if swallowed. 
R33:Danger of cumulative effects. 
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
R62:Risk of impaired fertility.
Safety Statements: 53-45-60-61 
S53:Avoid exposure - obtain special instructions before use. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S60:This material and its container must be disposed of as hazardous waste. 
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR: UN 1479 5.1/PG 2
WGK Germany: 3
RTECS: OG5425000
Hazardous Substances Data: 1314-41-6(Hazardous Substances Data)
Poison by intraperitoneal route. Moderately toxic by ingestion. Combustible by chemical reaction with reducing agents. An oxidizing agent. Explodes on contact with peroxyformic acid. Ignites on contact with dichloromethylsilane. Incandescent reaction with seleninyl chloride. One-percent fresh red lead decreases the explosion temperature of 2,4,6-trinitrotoluene to 192°C. Incompatible with Al, CsHC2, (F2 + glycerin), H2S3, (glycerin + HClO4), RbHC2, (Si + Al), Na, SO3, Ti, Zr. Mixtures of lead oxide with glycerin have been used as a jointing compound and may explode when exposed to powerful oxidizers. When heated to decomposition it emits toxic fumes of Pb.

Lead oxide Standards and Recommendations

OSHA PEL: TWA 0.05 mg(Pb)/m3
ACGIH TLV: TWA 0.15 mg(Pb)/m3
NIOSH REL: (Inorganic Lead) TWA 0.10 mg(Pb)/m3

Lead oxide Specification

  Lead oxide (CAS NO.1314-41-6) is red powder. It is stable and may react vigorously with reducing agents. It is insoluble in water and alcohol, soluble in nitric acid (the presence of hydrogen peroxide), acetic acid, hydrochloric acid and hot alkali. Synonyms of Lead oxide (CAS NO.1314-41-6) are C.I. 77578 ; C.I. Pigment Red 105 ; CI 77578 ; CI Pigment Red 105 ; EINECS 215-235-6 ; Gold satinobre ; HSDB 5801 ; Heuconin 5 ; Lead Oxide Red ; Lead orthoplumbate ; Lead oxide (3:4) ; Lead oxide (Pb3O4) ; Lead tetraoxide ; Lead oxide ; Mennige ; Mineral Orange ; Mineral Red ; Minium ; Minium Non-Setting RL 95 ; Minium Red ; Orange Lead ; Paris Red ; Pigment Red 105 ; Plumboplumbic oxide ; Red Lead ; Red Lead Oxide ; Red Lead Oxide (Pb3O4) ; Sandix ; Saturn Red ; Trilead tetraoxide ; TriLead oxide .

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