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Cas Database

Name	METHYL LACTATE	EINECS	208-930-0
CAS No.	547-64-8	Density	1.085 g/cm³
PSA	46.53000	LogP	-0.45980
Solubility	miscible, hydrolyses with water	Melting Point	-66°C
Formula	C₄H₈O₃	Boiling Point	145.3 °C at 760 mmHg
Molecular Weight	104.106	Flash Point	47.1 °C
Transport Information	UN 3272 3/PG 3	Appearance	clear colorless liquid
Safety	24	Risk Codes	10-36/37
Molecular Structure		Hazard Symbols	Xi
Synonyms	DL-Methyllactate;Methyl 2-hydroxypropanoate;Methyl 2-hydroxypropionate;Methyllactate;Methyl a-hydroxypropionate;NSC 406248;	Article Data	161

METHYL LACTATE Synthetic route

: 600-22-6
pyruvic acid methyl ester

: 547-64-8
methyl lactate

Conditions

Conditions	Yield
With magnesium(II) perchlorate; polymer-bound NADH (2a) In acetonitrile; benzene at 80℃; for 120h; Further byproducts given;	100%
With carbonylhydrido(tetrahydroborato)[bis(2-diphenylphosphinoethyl)-amino]ruthenium(II); hydrogen; sodium hydrogencarbonate In methanol at 25℃; under 7500.75 Torr; for 12h; Glovebox; Autoclave; chemoselective reaction;	98%
With hydrogen; Et4N	91%

: 67-56-1
methanol

: 547-64-8
methyl lactate

Conditions

Conditions	Yield
tetrabutoxytitanium at 170℃; for 4h; Product distribution / selectivity;	99.8%

: 67-56-1
methanol

: 96-26-4
dihydroxyacetone

: 547-64-8
methyl lactate

Conditions

Conditions	Yield
With tin containing MWW type β-zeolite In decane at 119.84℃; for 24h; Reagent/catalyst;	99%
With Y-zeolite H-USY-6 In water at 115℃; for 24h; Inert atmosphere;	96%
With Sn(salen) functionalized [OMIm]Br at 160℃; under 15001.5 Torr; for 2h; Inert atmosphere; Autoclave; chemoselective reaction;	95.5%

: 67-56-1
methanol

: 56-82-6
Glyceraldehyde

: 547-64-8
methyl lactate

Conditions

Conditions	Yield
With tin containing MWW type β-zeolite In decane at 119.84℃; for 24h; Reagent/catalyst;	99%
With Y-zeolite H-USY-6 In water at 115℃; for 48h; Inert atmosphere;	98%
With Sn(salen) functionalized [OMIm]Br at 160℃; under 15001.5 Torr; for 2h; Inert atmosphere; Autoclave; chemoselective reaction;	91.7%

: 75-07-0
acetaldehyde

: 547-64-8
methyl lactate

Conditions

Conditions	Yield
	98.8%

: 67-56-1
methanol

: 849585-22-4
LACTIC ACID

: 547-64-8
methyl lactate

Conditions

Conditions	Yield
With iron(III) sulfate; sulfuric acid for 3h; Heating;	97%
With ethenetetracarbonitrile for 48h; Ambient temperature;	88%
at 25 - 72℃; Product distribution / selectivity;	87%

: 67-56-1
methanol

: 56-81-5
glycerol

: 547-64-8
methyl lactate

Conditions

Conditions	Yield
With phosphotungstic acid at 130℃; for 4h; Reagent/catalyst; Autoclave; Inert atmosphere; Green chemistry;	96%
With Na/MgO at 160℃; under 30402 Torr; for 5h; Reagent/catalyst; Inert atmosphere;	80%
With magnesium oxide at 300℃; under 150015 Torr; for 1.5h; Reagent/catalyst; Temperature; Inert atmosphere; Sealed tube;	23.9 mol
With oxygen at 160℃; under 3750.38 Torr; Reagent/catalyst; Temperature; Autoclave;
With air; AuPd/carbon nanotubes + Sn-MCM-41-XS at 140℃; under 22502.3 Torr; for 4.5h; Catalytic behavior; Reagent/catalyst; Autoclave; Green chemistry;	90 %Chromat.

: 67-56-1
methanol

: 138-22-7
n-butyl lactate

: 547-64-8
methyl lactate

Conditions

Conditions	Yield
iodine for 15h; Heating;	90%

: 67-56-1
methanol

: 96-26-4
dihydroxyacetone

A: 547-64-8
methyl lactate

B: 35830-93-4
2-hydroxy-3-methoxypropionaldehyde

Conditions

Conditions	Yield
With calcined Sn-modified beta zeolite at 70℃; for 4h;	A 86% B n/a

: 67-56-1
methanol

: 78-97-7
2-hydroxy-propionitrile

: 547-64-8
methyl lactate

Conditions

Conditions	Yield
With hydrogenchloride; water at -10 - -5℃; for 4h; Reflux;	85.58%

METHYL LACTATE Chemical Properties

Synonyms: METHYL DL-LACTATE;METHYL (+/-) LACTATE;METHYL LACTATE;LACTIC ACID METHYL ESTER;DL-METHYL LACTATE;2-HYDROXYPROPANOIC ACID METHYL ESTER;1-hydroxyethanecarboxylicacid,methylester;2-hydroxy-propanoicacimethylester
EINECS: 208-930-0
METHYL LACTATE is the chemical compound with the formula C₄H₈O₃.Its Molecular Weight is 104.1.
Boiling point:35 °C (6 mmHg)
density:1.093 g/mL at 20 °C(lit.)
refractive index:n20/D 1.413
Flash point:49 °C
storage temp.:Flammables area
Water Solubility:miscible, hydrolyses

METHYL LACTATE Toxicity Data With Reference

ipr-rat LDLo:>2 g/kg

JPPMAB Journal of Pharmacy and Pharmacology. 11 (1959),150.

METHYL LACTATE Consensus Reports

Reported in EPA TSCA Inventory.

METHYL LACTATE Safety Profile

Slightly toxic by intraperitoneal route. When heated to decomposition it emits acrid smoke and irritating vapors.
Hazard Codes:Xi
METHYL LACTATE 's Risk Statements:
10:Flammable
36/37:Irritating to eyes and respiratory system
METHYL LACTATE 's Safety Statements:
24:Avoid contact with skin
RIDADR:UN 3272 3/PG 3
WGK Germany:1
RTECS:OD5670000
HazardClass:3.2
PackingGroup:III

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