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Magnesium,bromo(2-methylphenyl)-

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Name

Magnesium,bromo(2-methylphenyl)-

EINECS 213-250-2
CAS No. 932-31-0 Density 1.013 g/mL at 25 °C
PSA 0.00000 LogP 2.64080
Solubility N/A Melting Point N/A
Formula C7H7BrMg Boiling Point 110.6oC at 760mmHg
Molecular Weight 195.342 Flash Point −40 °F
Transport Information N/A Appearance N/A
Safety 16-26-33-36/37/39-45 Risk Codes 12-14-20/21/22-34-40
Molecular Structure Molecular Structure of 932-31-0 (O-TOLYLMAGNESIUM BROMIDE) Hazard Symbols HighlyF+;CorrosiveC
Synonyms

Magnesium,bromo-o-tolyl- (7CI,8CI);o-Tolylmagnesium bromide (6CI);2-Methylphenylmagnesium bromide;2-Tolylmagnesium bromide;Bromo(2-methylphenyl)magnesium;Bromo-o-tolylmagnesium;o-Methylphenylmagnesiumbromide;bromo-(o-tolyl)magnesium;bromo-o-tolylmagnesium;o-Tolylmagnesium bromide solution;

Article Data 15

Magnesium,bromo(2-methylphenyl)- Specification

The Magnesium,bromo(2-methylphenyl)-, with the CAS registry number 932-31-0 and EINECS registry number 213-250-2, has the systematic name of bromo-(o-tolyl)magnesium. It belongs to the following product categories:Classes of Metal Compounds; Grignard Reagents; Grignard Reagents & Alkyl Metals; Mg (Magnesium) Compounds; Synthetic Organic Chemistry; Typical Metal Compounds; Aryl; Grignard Reagents; Organometallic Reagents. And the molecular formula of the chemical is C7H7BrMg.

The characteristics of Magnesium,bromo(2-methylphenyl)- are as followings: (1)H-Bond Donor 0; (2)H-Bond Acceptor 2; (3)Rotatable Bond Count 0; (4)Exact Mass 193.958155; (5)MonoIsotopic Mass 193.958155; (6)Topological Polar Surface Area 0; (7)Heavy Atom Count 9; (8)Formal Charge 0; (9)Complexity 145; (10)Isotope Atom Count 0; (11)Defined Atom StereoCenter Count 0; (12)Undefined Atom StereoCenter Count 0; (13)Defined Bond StereoCenter Count 0; (14)Undefined Bond StereoCenter Count 0; (15)Covalently-Bonded Unit Count 3.

Uses of Magnesium,bromo(2-methylphenyl)-: It can react with cyclohex-2-enone to produce 3-(2-tolyl)cyclohexanone. This reaction will need reagent Cu2I2, and the menstruum diethyl ether. And the yield is about 85%. 

You should be cautious while dealing with this chemical. It is a kind of highly flammable chemical which reacts violently with water, and it is harmful by inhalation, in contact with skin and if swallowed. WHat's more, it may also cause burns and carcinogenic effect. Therefore, you had better take the following instructions: Keep away from sources of ignition - No smoking; Take precautionary measures against static discharges; Wear suitable protective clothing, gloves and eye/face protection, and if in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice; In case of accident or if you feel unwell, seek medical advice immediately (show label where possible).

Addtionally, the following datas could be converted into the molecular structure:
(1)SMILES: Br[Mg]c1ccccc1C
(2)InChI: InChI=1/C7H7.BrH.Mg/c1-7-5-3-2-4-6-7;;/h2-5H,1H3;1H;/q;;+1/p-1/rC7H7BrMg/c1-6-4-2-3-5-7(6)9-8/h2-5H,1H3
(3)InChIKey: DVXDIGKNJYSMFM-XGJOHVQZAP

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