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Mancozeb

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Mancozeb

EINECS N/A
CAS No. 8018-01-7 Density 1.92 g/cm3
PSA 88.24000 LogP 0.60850
Solubility practically insoluble in most organic solvents Melting Point 192-194 ºC
Formula C4 H6 Mn N2 S4 Boiling Point 308.2 °C at 760 mmHg
Molecular Weight 541.066 Flash Point 140.2 °C
Transport Information UN 2210 Appearance Grayish-yellow powder
Safety 8-24/25-46 Risk Codes R37;R43   
Molecular Structure Molecular Structure of 8018-01-7 (Mancozeb) Hazard Symbols
Synonyms

MICENE;CRITTOX;marzin;fore;MANCO;Manaeb;MANZEB;f2966;

Article Data 3

Mancozeb Consensus Reports

EPA Genetic Toxicology Program. Zinc and its compounds, as well as manganese and its compounds, are on the Community Right-To-Know List.

Mancozeb Standards and Recommendations

OSHA PEL: CL 5 mg(Mn)/m3
ACGIH TLV: TWA 5 mg(Mn)/m3

Mancozeb Specification

Mancozeb, with the CAS No.8018-01-7, has the Synonyms of Dithane; MANCOZEB; 1,2-Ethanedicarbamic acid, tetrathio-; CID3034368; ethylenebisdithiocarbamate manganese-zinc; NCGC00168344-01; LS-63091; C013099; manganese(2+) ethane-1,2-diylbis(dithiocarbamate) zinc ethane-1,2-diylbis(dithiocarbamate). Mancozeb, a ethylenebis(dithiocarbamate) fungicide, is widely used in agriculture, including moriculture and sericulture. It is registered as a foliar application to fruit (pears, apples, grapes), vegetables (tomatoes,potatoes, onions, carrots, celery, melons), sugar beets, ginseng, wheat and ornamentals.

Physical properties about Mancozeb are: (1)ACD/LogP: 1.656; (2)ACD/LogD (pH 5.5): -3.09; (3)ACD/LogD (pH 7.4): -3.09; (4)ACD/BCF (pH 5.5): 1.00; (5)ACD/BCF (pH 7.4): 1.00; (6)ACD/KOC (pH 5.5): 1.00; (7)ACD/KOC (pH 7.4): 1.00; (8)#H bond acceptors: 2; (9)#H bond donors: 2; (10)#Freely Rotating Bonds: 3; (11)Flash Point: 140.2 °C; (12)Enthalpy of Vaporization: 54.88 kJ/mol; (13)Boiling Point: 308.2 °C at 760 mmHg; (14)Vapour Pressure: 0.000692 mmHg at 25°C

When you are using this chemical, please be cautious about it as the following:
1. Keep container dry;
2. Avoid contact with skin and eyes;
3. If swallowed, seek medical advice immediately and show this container or label;

You can still convert the following datas into molecular structure:
(1)SMILES:[Mn+2].[Zn+2].[S-]C(=S)NCCNC(=S)[S-].[S-]C(=S)NCCNC([S-])=S;
(2)Std. InChI:InChI=1S/2C4H8N2S4.Mn.Zn/c2*7-3(8)5-1-2-6-4(9)10;;/h2*1-2H2,(H2,5,7,8)(H2,6,9,10);;/q;;2*+2/p-4;
(3)Std. InChIKey:CHNQZRKUZPNOOH-UHFFFAOYSA-J

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rabbit LD50 skin > 5gm/kg (5000mg/kg)   Pesticide Manual. Vol. 9, Pg. 530, 1991.
rat LD50 oral 5gm/kg (5000mg/kg)   "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86Vol. A251, Pg. 1986,
rat LD50 skin > 10gm/kg (10000mg/kg)   "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86Vol. A251, Pg. 1986,

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