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Merphenyl nitrate

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Name

Merphenyl nitrate

EINECS 200-242-9
CAS No. 8003-05-2 Density N/A
PSA 75.28000 LogP 1.72280
Solubility slightly Melting Point 175-185 °C (dec.)(lit.)

Formula C6H6HgO•C6H5HgNO3 Boiling Point N/A
Molecular Weight 634.42 Flash Point N/A
Transport Information N/A Appearance White to pale yellow powder
Safety Poison by intravenous and subcutaneous routes. When heated to decomposition it emits very toxic fumes of Hg and NOx. See also MERCURY COMPOUNDS, INORGANIC; MERCURY COMPOUNDS, ORGANIC and NITRATES. Risk Codes 25-34-48/24/25-50/53
Molecular Structure Molecular Structure of 8003-05-2 (PHENYLMERCURIC NITRATE) Hazard Symbols Toxic by ingestion, inhalation, and skin absorption.
Synonyms

Gyne-merfen;phenylmercury nitrate hydrate;DZ;Mercury, hydroxyphenyl-, cmpd. with nitratophenylmercury (1:1);6509-33-7;Mercury, hydroxy(nitrato)diphenyldi-;Phenylmercuric nitrate, basic;Merfen-styli;Nitrate phenyl mercurique [French];Mercury, hydroxyphenyl-, mixt. with Phenylmercuric nitrate;Mercury nitratophenyl-, cmpd. with hydroxyphenylmercury (1:1);nitric acid; phenylmercury; hydrate;Phenylmercuric Nitrate (basic);MERCURY, HYDROXY-PHENYL-, cmpd. with NITRATOPHENYLMERCURY (1:1);NITRATE PHENYL MERCURIQUE;MERPHENE;PHERMERNITE;PHEMERN-ITE;

 

Merphenyl nitrate Chemical Properties

IUPAC Name: Hydroxy-phenyl-mercury; nitrooxy-phenyl-mercury
Synonyms: Mercury, hydroxyphenyl-, mixt. with Phenylmercuric nitrate ; Phenylmercuric nitrate, basic ; Phenylmercury nitrate
CAS NO: 8003-05-2
Molecular Formula of Merphenyl nitrate (CAS NO.8003-05-2) : C12H11Hg2NO4
Molecular Weight of Merphenyl nitrate (CAS NO.8003-05-2) : 634.4
Molecular Structure of Merphenyl nitrate (CAS NO.8003-05-2) :
EINECS: 200-242-9
Mol File: 8003-05-2.mol
Merck : 14,7302
Melting point: 175-185 °C (dec.)(lit.)
Appearance: white flake crystal pearl.
Solubility: slightly soluble in alcohol, very slightly soluble in water, almost insoluble in ether can be slowly dissolved in glycerol.

Merphenyl nitrate Uses

 Merphenyl nitrate (CAS NO.8003-05-2) is used as preservatives and contraceptive materials in the pharmaceutical industry.

Merphenyl nitrate Production

Raw materials: PHENYLMERCURIC ACETATE 
 Merphenyl nitrate (CAS NO.8003-05-2) can be obtained by the reaction of Mercuric phenyl acetate and Sodium nitrate .

Merphenyl nitrate Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intravenous 27mg/kg (27mg/kg)   Quarterly Journal of Pharmacy & Pharmacology. Vol. 12, Pg. 212, 1939.
mouse LD50 subcutaneous 45mg/kg (45mg/kg)   Quarterly Journal of Pharmacy & Pharmacology. Vol. 12, Pg. 212, 1939.
rat LD50 subcutaneous 56mg/kg (56mg/kg)   Quarterly Journal of Pharmacy & Pharmacology. Vol. 12, Pg. 212, 1939.

 

Merphenyl nitrate Consensus Reports

Mercury and its compounds are on the Community Right-To-Know List.

Merphenyl nitrate Safety Profile

Poison by intravenous and subcutaneous routes. When heated to decomposition it emits very toxic fumes of Hg and NOx. See also MERCURY COMPOUNDS, INORGANIC; MERCURY COMPOUNDS, ORGANIC and NITRATES.
Hazard Codes ToxicT,DangerousN
Risk Statements 34-48/24/25-50/53
R:48/24/25: Toxic: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed 
R34:Causes burns. 
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements 23-24/25-37-45-60-61
S23:Do not breathe vapour. 
S24/25:Avoid contact with skin and eyes. 
S37:Wear suitable gloves. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S60:This material and its container must be disposed of as hazardous waste. 
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR UN 1895 6.1/PG 2
WGK Germany 3
RTECS OW8575000
HazardClass 6.1
PackingGroup II

Merphenyl nitrate Standards and Recommendations

OSHA PEL: CL 0.1 mg(Hg)/m3 (skin)
ACGIH TLV: TWA 0.1 mg(Hg)/m3 (skin); BEI: 35 µg/g creatinine total inorganic mercury in urine preshift; 15 µg/g creatinine total inorganic mercury in blood at end of shift at end of workweek.
DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans
NIOSH REL: (Mercury, Aryl and Inorganic) CL 0.1 mg/m3 (skin)

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