Basic information
- Name:
Methyl salicylate
- CAS No.:
119-36-8
- Molecular Structure:
- Formula:
- C8H8O3
- Synonyms:
- Gaultheria Oil, artificial;Benzoic acid,2-hydroxy-,esters,methyl ester;Teaberry oil;Gaultheriaoel;2-(Methoxycarbonyl)phenol;Wintergruenoel;o-Hydroxybenzoic acid, methyl ester;Natural Wintergreen Oil;Betula;Salicylic acid, methyl ester;Methyl salicylate (JP14/NF);Oil of Wintergreen;Methyl salicylate BP;Methyl Hydroxy benzoate;Methyl salicylic acid;methyl salicylate;2-carbomethoxyphenol; methyl o-hydroxybenzoate;Wintergreen oil;Methyl 2-hydroxybenzoate;Gaultheria oil;Metylester kyseliny salicylove;Methyl o-hydroxybenzoate;Benzoic acid, 2-hydroxy-, methyl ester;Spicewood Oil;Flucarmit;
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Chemistry
IUPAC Name: methyl 2-hydroxybenzoate
Empirical Formula: C8H8O3
Molecular Weight: 152.1473g/mol
EINECS: 204-317-7
Structure of Methyl salicylate (CAS NO.119-36-8):
Index of Refraction: 1.547
Molar Refractivity: 39.9 cm3
Molar Volume: 125.7 cm3
Polarizability: 15.82×10-24cm3
Surface Tension: 45.7 dyne/cm
Density: 1.209 g/cm3
Flash Point: 86.8 °C
Enthalpy of Vaporization: 47.71 kJ/mol
Melting Point: -8 °C
Boiling Point: 222 °C at 760 mmHg
Vapour Pressure: 0.07 mmHg at 25°C
Water Solubility: 0.07 g/100 mL (20 ºC)
Stability: Stable. Incompatible with strong oxidizing agents, strong bases.
Product Categories: INORGANIC & ORGANIC CHEMICALS;FINE Chemical & INTERMEDIATES;Cosmetic Ingredients & Chemicals
Canonical SMILES: COC(=O)C1=CC=CC=C1O
InChI: InChI=1S/C8H8O3/c1-11-8(10)6-4-2-3-5-7(6)9/h2-5,9H,1H3
InChIKey: OSWPMRLSEDHDFF-UHFFFAOYSA-N
Uses
Methyl salicylate is commonly used as spices of food, toothpaste and cosmetics.It is also used to produce antalgesic drugs, pesticides, rubbing agent, ink, etc.
Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| child | LDLo | oral | 228mg/kg (228mg/kg) | LUNGS, THORAX, OR RESPIRATION: DYSPNEA GASTROINTESTINAL: NAUSEA OR VOMITING | American Journal of Diseases of Children. Vol. 69, Pg. 37, 1945. |
| child | LDLo | oral | 700mg/kg (700mg/kg) | PERIPHERAL NERVE AND SENSATION: FLACCID PARALYSIS WITHOUT ANESTHESIA (USUALLY NEUROMUSCULAR BLOCKAGE) LUNGS, THORAX, OR RESPIRATION: DYSPNEA BEHAVIORAL: GENERAL ANESTHETIC | Archives of Disease in Childhood. Vol. 28, Pg. 475, 1953. |
| dog | LD50 | oral | 2100mg/kg (2100mg/kg) | LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES GASTROINTESTINAL: NAUSEA OR VOMITING GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" | Food and Cosmetics Toxicology. Vol. 16, Pg. 821, 1978. |
| dog | LDLo | subcutaneous | 2250mg/kg (2250mg/kg) | Food and Cosmetics Toxicology. Vol. 16, Pg. 821, 1978. | |
| guinea pig | LD50 | oral | 700mg/kg (700mg/kg) | "Industrial Hygiene and Toxicology," 2nd ed., Patty, F.A., ed., New York, John Wiley & Sons, Inc., 1958-63Vol. 2, Pg. 1897, 1963. | |
| guinea pig | LDLo | subcutaneous | 1500mg/kg (1500mg/kg) | FAO Nutrition Meetings Report Series. Vol. 44A, Pg. 63, 1967. | |
| human | LDLo | oral | 506mg/kg (506mg/kg) | "Merck Index; an Encyclopedia of Chemicals, Drugs, and Biologicals", 11th ed., Rahway, NJ 07065, Merck & Co., Inc. 1989Vol. 11, Pg. 961, 1989. | |
| infant | LDLo | oral | 1480mg/kg (1480mg/kg) | LUNGS, THORAX, OR RESPIRATION: RESPIRATORY STIMULATION GASTROINTESTINAL: NAUSEA OR VOMITING | American Journal of the Medical Sciences. Vol. 193, Pg. 772, 1937. |
| man | LDLo | oral | 101mg/kg (101mg/kg) | BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD GASTROINTESTINAL: NAUSEA OR VOMITING | American Journal of the Medical Sciences. Vol. 193, Pg. 772, 1937. |
| man | LDLo | oral | 1329mg/kg (1329mg/kg) | BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD BEHAVIORAL: COMA BLOOD: HEMORRHAGE | Clinical Toxicology. Vol. 6, Pg. 189, 1973. |
| man | LDLo | unreported | 522mg/kg (522mg/kg) | "Poisoning; Toxicology, Symptoms, Treatments," 2nd ed., Arena, J.M., Springfield, IL, C.C. Thomas, 1970Vol. 2, Pg. 73, 1970. | |
| mouse | LD50 | oral | 1110mg/kg (1110mg/kg) | Journal of Pharmacology and Experimental Therapeutics. Vol. 132, Pg. 207, 1961. | |
| rabbit | LD50 | oral | 1300mg/kg (1300mg/kg) | Food and Cosmetics Toxicology. Vol. 16, Pg. 821, 1978. | |
| rabbit | LDLo | subcutaneous | 4250mg/kg (4250mg/kg) | Food and Cosmetics Toxicology. Vol. 16, Pg. 821, 1978. | |
| rat | LD50 | oral | 887mg/kg (887mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) | Food and Cosmetics Toxicology. Vol. 2, Pg. 327, 1964. |
| women | LDLo | oral | 355mg/kg (355mg/kg) | BEHAVIORAL: COMA LUNGS, THORAX, OR RESPIRATION: RESPIRATORY STIMULATION GASTROINTESTINAL: NAUSEA OR VOMITING | American Journal of the Medical Sciences. Vol. 193, Pg. 772, 1937. |
Safety Profile
Hazard Codes: 
Xn
Risk Statements: 22-36/38-36/37/38
R22:Harmful if swallowed.
R36/38:Irritating to eyes and skin.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36-24/25
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36:Wear suitable protective clothing.
S24/25:Avoid contact with skin and eyes.
RIDADR: 3082
WGK Germany: 1
RTECS: VO4725000
F: 8
HazardClass: 6.1(b)
PackingGroup: III
Hazardous Substances Data: 119-36-8(Hazardous Substances Data)
Specification
Methyl salicylate , its cas register number is 119-36-8. It also can be called 2-(Methoxycarbonyl)phenol ; 2-Carbomethoxyphenol ; 2-Hydroxybenzoic acid methyl ester ; Analgit ; Benzoic acid, 2-hydroxy-, methyl ester ; Betula ;
Betula Lenta ; Betula oil ; Exagien ; Flucarmit ; Gaultheria oil ; Gaultheria oil, artificial ; Gaultheriaoel ; Methyl 2-hydroxybenzoate ; Methyl o-hydroxybenzoate ; Methylester kyseliny salicylove ; Metylester kyseliny salicylove ; Natural wintergreen oil ; Oil of wintergreen ; Salicylic acid, methyl ester ; Synthetic wintergreen oil ; Teaberry oil ; Wintergreen oil ;
Wintergreen oil, synthetic ; Wintergruenoel ; o-Anisic acid ; o-Hydroxybenzoic acid, methyl ester . Methyl salicylate (CAS NO.119-36-8) is a colourless liquid with an odour of wintergreen.
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