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Basic information

  • Name:
  • Methyltrimethoxysilane

  • CAS No.:
  • 1185-55-3

  • Molecular Structure:
  • Formula:
  • C4H12O3Si
  • Molecular Weight:
  • 136.25
  • Deleted CAS:
  • 106153-30-4|120250-60-4
  • Synonyms:
  • (Trimethoxysilyl)methane;Silane,trimethoxymethyl-;Dynasylan MTMS;Glasca B;Methylsilicon trimethoxide (MeSi(OMe)3);NUCSilicone A 163;Silquest A 163;Silquest A 1630;Trimethoxymethylsilane;Methyltrimethoxysilane, Trimethoxy methyl silane;
  • EINECS:
  • 214-685-0
  • Density:
  • 0.911 g/cm3
  • Melting Point:
  • <-70 ºC
  • Boiling Point:
  • 102.5 ºC at 760 mmHg
  • Flash Point:
  • 11.1 ºC
  • Solubility:
  • decomposes in water
  • Appearance:
  • colourless liquid
  • Hazard Symbols:
  • FlammableF
  • Risk Codes:
  • 11
  • Safety Description:
  • 16 Details
  • Transport Information:
  • UN 1993 3/PG 2

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Chemistry


IUPAC Name: Trimethoxy(methyl)silane
Molecular Formula: C4H12O3Si
Molecular Weight: 136.22 g/mol
SMILES: O(C)[Si](OC)(OC)C Copy 
InChI: InChI=1/C4H12O3Si/c1-5-8(4,6-2)7-3/h1-4H3 
EINECS: 214-685-0
Classification Code: Organometallic; Skin / Eye Irritant
Product Categories: Alkyl; Organics; Silicone series; Functional Materials; Si (Classes of Silicon Compounds); Silane Coupling Agents; Silane Coupling Agents (Intermediates); Si-O Compounds; Trialkoxysilanes; Alkoxy Silanes; Crosslinkers; Crosslinking Agents
storage temperature: 2-8 °C
Stability: Stable, but moisture sensitive. Highly flammable. Incompatible with water, strong acids, strong oxidizing agents. 
Water Solubility: decomposes
Sensitive: Moisture Sensitive
Index of Refraction: 1.379 
Molar Refractivity: 34.53 cm3 
Molar Volume: 149.3 cm3
Surface Tension: 18.4 dyne/cm 
Density: 0.911 g/cm
Flash Point: 11.1 °C 
Enthalpy of Vaporization: 32.75 kJ/mol 
Boiling Point: 102.5 °C at 760 mmHg 
Melting Point: <-70 °C
Vapour Pressure of Methyltrimethoxysilane (CAS NO.1185-55-3): 38.8 mmHg at 25 °C

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rabbit LD skin > 10mL/kg (10mL/kg)   Union Carbide Data Sheet. Vol. 1/17/1972,
rat LD50 oral 12300uL/kg (12.3mL/kg)   Union Carbide Data Sheet. Vol. 1/17/1972,

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Mildly toxic by ingestion. A skin and eye irritant. When heated to decomposition it emits acrid smoke and fumes.
Hazard Codes: FlammableF
Risk Statements: 11 
R11:Highly flammable.
Safety Statements: 16 
S16:Keep away from sources of ignition.
RIDADR: UN 1993 3/PG 2
WGK Germany: 3
RTECS: VV4650000
HazardClass: 3
PackingGroup of Methyltrimethoxysilane (CAS NO.1185-55-3): II

Specification

  Methyltrimethoxysilane (CAS NO.1185-55-3), its Synonyms are Silane, methyltrimethoxy- ; Silane, trimethoxymethyl- ; Trimethoxymethylsilane ; Union carbide A-163 . It is colorless clear liquid.

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