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Molybdenum Trioxide

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Name

Molybdenum Trioxide

EINECS 215-204-7
CAS No. 1313-27-5 Density 4.692 g/cm3
PSA 51.21000 LogP -0.35640
Solubility 0.5 g/L (20 °C) in water Melting Point 1155 °C
Formula MoO3 Boiling Point 1155oC
Molecular Weight 143.938 Flash Point 1155oC subl.
Transport Information N/A Appearance pale yellowish-green powder
Safety 22-23-25 Risk Codes 36/37-48/20/22
Molecular Structure Molecular Structure of 1313-27-5 (Molybdenum(VI) oxide) Hazard Symbols HarmfulXn,IrritantXi
Synonyms

Bouen SKN301;JCPDS 35-0609;MFR;Molybdena;Molybdenumoxide (Mo4O12);Molybdenum oxide (MoO3), tetramer;Molybdenum trioxide;Molybdenum trioxidetetramer;Molybdenum(VI) oxide;Molybdic anhydride;Molybdic oxide;NSC 215191;Pol-U;Molybdenum(Ⅵ)oxide;

Article Data 2

Molybdenum Trioxide Synthetic route

126031-97-8

{MoCl3(C5H4N)2(H2O)}

1313-27-5

molybdenum trioxide

Conditions
ConditionsYield
decompn. at 390-400°C;
75-15-0

carbon disulfide

1313-27-5

molybdenum trioxide

103-49-1

dibenzylamine

C30H28Mo2N2O2S6

Conditions
ConditionsYield
Stage #1: molybdenum trioxide With sodium hydrogen sulfide In water for 0.5h; Sealed tube;
Stage #2: carbon disulfide; dibenzylamine With hydrogenchloride In water; toluene at 20 - 100℃; for 4.5h; Sealed tube;
93%
110-91-8

morpholine

86119-84-8, 7664-38-2

phosphoric acid

1313-27-5

molybdenum trioxide

HMo5O23P2(6-)*5C4H9NO*5H2O*5H(1+)

Conditions
ConditionsYield
at 25℃; for 2191.5h; pH=Ca. 4;70%
2052-49-5

tetra(n-butyl)ammonium hydroxide

1313-27-5

molybdenum trioxide

di(tetra-n-butylammonium) dimolybdate

Conditions
ConditionsYield
In water at 20℃; for 24h;63%
917-23-7

5,15,10,20-tetraphenylporphyrin

1313-27-5

molybdenum trioxide

28780-74-7

(hydroxy)(oxo)(5,10,15,20-tetraphenylporphyrinato)molybdenum(v)

Conditions
ConditionsYield
With phenol at 180.84℃; for 4h;60%
7647-01-0

hydrogenchloride

thorium(IV) nitrate pentahydrate

1313-27-5

molybdenum trioxide

Th(4+)*MoO4(2-)*2Cl(1-)*5H2O

Conditions
ConditionsYield
at 230℃; for 24h; Autoclave;50%

sodium arsenate dodecahydrate

56643-83-5

1,4-bis(imidazol-l-yl-methyl)benzene

1313-27-5

molybdenum trioxide

As2Mo6O27(8-)*2H2O*8H(1+)*2C14H14N4

Conditions
ConditionsYield
With copper(II) nitrate trihydrate In water at 160℃; for 144h; pH=Ca. 3.5; Autoclave; High pressure;38%

potassium 4-(2-decyltetradecyl)-1-piperazinedithiocarbamate

1313-27-5

molybdenum trioxide

C58H114Mo2N4O2S6

Conditions
ConditionsYield
Stage #1: molybdenum trioxide With sodium hydrogensulfide In water at 25℃; for 3h; Inert atmosphere;
Stage #2: potassium 4-(2-decyltetradecyl)-1-piperazinedithiocarbamate With hydrogenchloride In tetrahydrofuran; water at 90℃; for 18h;
36.5%

nickel(II) carbonate hydroxide

1313-27-5

molybdenum trioxide

nickel molybdate

Conditions
ConditionsYield
In water at 90℃; for 20h;
1313-27-5

molybdenum trioxide

75-19-4

cyclopropane

Mo(x)O(y)(C3H4)(1+)

Conditions
ConditionsYield
In neat (no solvent, gas phase) byproducts: Mo(x)O(y)(CH2)(1+), Mo(x)O(y)(C2H4)(1+), Mo(x)O(y)(CH4)(1+); study on formation of molybdenum carbene complexes; monitored by ICR mass spectrometer;

Molybdenum Trioxide Consensus Reports

Reported in EPA TSCA Inventory.

Molybdenum Trioxide Standards and Recommendations

OSHA PEL: TWA 5 mg(Mo)/m3
ACGIH TLV: TWA Soluble Compounds: TWA 0.5 mg(Mo)/m3 Confirmed Animal Carcinogen with Unknown Relevance to Humans

Molybdenum Trioxide Specification

The Molybdenum trioxide, with the CAS registry number 1313-27-5, is also known as Molybdenum(VI) oxide. It belongs to the product category of Inorganics. Its EINECS registry number is 215-204-7. This chemical's molecular formula is MoO3 and molecular weight is 143.94. Its IUPAC name is called trioxomolybdenum. This chemical's classification codes are Human Data; Mutation data; Tumor data.

Physical properties of Molybdenum trioxide: (1)H-Bond Donor: 0; (2)H-Bond Acceptor: 3; (3)Rotatable Bond Count: 0; (4)Exact Mass: 145.890152; (5)MonoIsotopic Mass: 145.890152; (6)Topological Polar Surface Area: 51.2; (7)Heavy Atom Count: 4; (8)Formal Charge: 0; (9)Complexity: 61.8; (10)Covalently-Bonded Unit Count: 1.

Preparation: this chemical can be prepared by ammonium molybdate.

Uses of Molybdenum trioxide: it is used to manufacture molybdenum metal, which serves as an additive to steel and corrosion-resistant alloys. It is also a component of the co-catalyst used in the industrial production of acrylonitrile by the oxidation of propene and ammonia. Because of its layered structure and the ease of the Mo(VI)/Mo(V) couple, MoO3 is of interest in electrochemical devices and displays.

When you are using this chemical, please be cautious about it as the following:
This chemical may cause damage to health and may cause inflammation to the skin or other mucous membranes. It is harmful by inhalation and if swallowed. In addition, it is irritating to eyes and respiratory system. You should not breathe its gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer). What's more, you must avoid contacting it with eyes.

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: O=[Mo](=O)=O
(2)InChI: InChI=1S/Mo.3O
(3)InChIKey: JKQOBWVOAYFWKG-UHFFFAOYSA-N

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
guinea pig LD75 intraperitoneal 400mg/kg (400mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
man TCLo inhalation 6mg/m3/4Y (6mg/m3) LUNGS, THORAX, OR RESPIRATION: "FIBROSIS, FOCAL (PNEUMOCONIOSIS)"

LUNGS, THORAX, OR RESPIRATION: COUGH
National Technical Information Service. Vol. AEC-TR-6710,
mouse LD50 intraperitoneal 141mg/kg (141mg/kg) LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 9(6), Pg. 40, 1965.
mouse LD50 subcutaneous 94mg/kg (94mg/kg)   Zhurnal Vsesoyuznogo Khimicheskogo Obshchestva im. D.I. Mendeleeva. Journal of the D.I. Mendeleeva All-Union Chemical Society. Vol. 19, Pg. 186, 1974.
rat LC50 inhalation > 5840mg/m3/4H (5840mg/m3)   Cyprus Copper Company. Vol. 18JUN1991,
rat LD50 oral 2689mg/kg (2689mg/kg)   Cyprus Copper Company. Vol. 18JUN1991,
rat LD50 skin > 2gm/kg (2000mg/kg)   Cyprus Copper Company. Vol. 18JUN1991,

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