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Molybdenum trioxide (1313-27-5)

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Chemistry

Molecular formula: MoO3
Molar mass: 143.94 g/mol
EINECS: 215-204-7
Melting point: 795 °C(lit.)
Water solubility: 0.5 g/L (20 ºC)
Appearance: Colorless to white or yellow odorless solid
Product categories of Molybdenum trioxide(CAS NO.1313-27-5): Inorganics
Structure of Molybdenum trioxide(CAS NO.1313-27-5):
                                                                        
H-Bond Donor: 0
H-Bond Acceptor: 3
IUPAC Name: Trioxomolybdenum
Canonical SMILES: O=[Mo](=O)=O
InChI: InChI=1S/Mo.3O 
InChIKey: JKQOBWVOAYFWKG-UHFFFAOYSA-N

Uses

Its chief application is as an oxidation catalyst and as a raw material for the production of molybdenum metal. Molybdenum trioxide(CAS NO.1313-27-5) is used to manufacture molybdenum metal, which serves as an additive to steel and corrosion-resistant alloys. The relevant conversion entails treatment is hydrogen at elevated temperatures.It is of interest in electrochemical devices and displayswith its layered structure and the ease of the Mo(VI)/Mo(V) couple.And it is also a component of the co-catalyst used in the industrial production of acrylonitrile by the oxidation of propene and ammonia.

Production

Molybdenum trioxide(1313-27-5) is produced on the largest scale of any molybdenum compound, and produced industrially by burning molybdenum disulfide (2 MoS2 + 7 O2 → 2 MoO3 + 4 SO2 ).The laboratory synthesis entails the acidification of aqueous solutions of sodium molybdate with perchloric acid (Na2MoO4 + H2O + 2 HClO4 → MoO3(H2O)2 + 2 NaClO4 ).

Toxicity Data With Reference
Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
guinea pig LD75 intraperitoneal 400mg/kg (400mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
man TCLo inhalation 6mg/m3/4Y (6mg/m3) LUNGS, THORAX, OR RESPIRATION: "FIBROSIS, FOCAL (PNEUMOCONIOSIS)"

LUNGS, THORAX, OR RESPIRATION: COUGH
National Technical Information Service. Vol. AEC-TR-6710,
mouse LD50 intraperitoneal 141mg/kg (141mg/kg) LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 9(6), Pg. 40, 1965.
mouse LD50 subcutaneous 94mg/kg (94mg/kg)   Zhurnal Vsesoyuznogo Khimicheskogo Obshchestva im. D.I. Mendeleeva. Journal of the D.I. Mendeleeva All-Union Chemical Society. Vol. 19, Pg. 186, 1974.
rat LC50 inhalation > 5840mg/m3/4H (5840mg/m3)   Cyprus Copper Company. Vol. 18JUN1991,
rat LD50 oral 2689mg/kg (2689mg/kg)   Cyprus Copper Company. Vol. 18JUN1991,
rat LD50 skin > 2gm/kg (2000mg/kg)   Cyprus Copper Company. Vol. 18JUN1991,
Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by ingestion, subcutaneous, and intraperitoneal routes. Human systemic effects by inhalation: pulmonary fibrosis and cough. Questionable carcinogen with experimental neoplastigenic data. A powerful irritant. Explodes on contact with molten magnesium. Violent reaction with interhalogens (e.g., bromine pentafluoride, chlorine trifluoride). Incandescent reaction with hot sodium, potassium, or lithium. When heated to decomposition it emits toxic fumes of Mo. See also MOLYBDENUM COMPOUNDS.
Hazard Codes: Xn,Xi
Risk Statements: 36/37-48/20/22
20:  Harmful by inhalation
22:  Harmful if swallowed
36:  Irritating to the eyes
37:  Irritating to the respiratory system
48:  Danger of serious damage to health by prolonged exposure
Safety Statements: 22-23-25
22:  Do not breathe dust
23:  Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) 
25:  Avoid contact with eyes

Standards and Recommendations

OSHA PEL: TWA 5 mg(Mo)/m3
ACGIH TLV: TWA Soluble Compounds: TWA 0.5 mg(Mo)/m3 Confirmed Animal Carcinogen with Unknown Relevance to Humans

Specification

 Molybdenum trioxide ,its cas register number is 1313-27-5.It also can be called Molybdenum(VI) oxide ; Molybdic trioxide ; Molybdic oxide ; Molybdic anhydride ; Trioxomolybdenum and molybdenum, trioxo- .It is hazardous,so the first aid measures and others should be known.Such as: When on the skin: first,should  flush skin with plenty of water immediately for at least 15 minutes while removing contaminated clothing. Secondly,Get shoesmedical aid . Or in the eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.Then get medical aid soon.While ,it's Inhaled: Remove from exposure and move to fresh air immediately.Give artificial respiration while not breathing. When breathing is difficult, give oxygen. And as soon as to get medical aid. Then you have the ingesting of the product : Wash mouth out with water,and get medical aid immediately.Notes to physician: Treat supportively and symptomatically.In addition, Molybdenum trioxide(CAS NO.1313-27-5) can be stable under normal temperature and pressure conditions.It is not compatible with strong oxidizing agents, strong acids, active metals, bromine trifluoride, chlorine trifluoride, magnesium, lithium, and you must not take it with incompatible materials.

Basic information

  • Product Name:

    Molybdenum trioxide

  • CAS No:1313-27-5
  • Formula:MoO3
  • Synonyms:Bouen SKN301; JCPDS 35-0609; MFR; Mo 1202T; Molybdena; Molybdenum oxide; Molybdenumoxide (Mo4O12); Molybdenum oxide (Mo5O15); Molybdenum oxide (MoO3), tetramer;Molybdenum trioxide; Molybdenum trioxide pentamer; Molybdenum trioxidetetramer; Molybdenum(VI) oxide; Molybdenum(VI) trioxide; Molybdic acidanhydride; Molybdic anhydride; Molybdic oxide; NSC 215191; Pol-U
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