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Monoacetin

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Name

Monoacetin

EINECS 247-704-6
CAS No. 26446-35-5 Density 1.21
PSA 66.76000 LogP -1.09730
Solubility soluble Melting Point 3 °C
Formula C5H10O4 Boiling Point 258 °C
Molecular Weight 134.13 Flash Point 145 °C
Transport Information N/A Appearance Clear colorless to pale yellow viscous liquid
Safety 24/25 Risk Codes 68
Molecular Structure Molecular Structure of 26446-35-5 (Monoacetin) Hazard Symbols N/A
Synonyms

Acetin, mono- (6CI,7CI,8CI);Acetin;Eastman 9-45;Glycerin monoacetate;Glycerine monoacetate;Glycerol acetate;Glycerol monoacetate;Glyceryl acetate;Glyceryl monoacetate;

 

Monoacetin Chemical Properties

The structure of Monoacetin (CAS NO.26446-35-5):

IUPAC Name: 2,3-Dihydroxypropyl acetate 
Molecular Weight: 134.1305 g/mol
Molecular Formula: C5H10O4 
Density: 1.22 g/cm3 
Melting Point: 3 °C
Boiling Point: 253 °C at 760 mmHg 
Flash Point: 107.3 °C
Index of Refraction: 1.458
Molar Refractivity: 30.01 cm3
Molar Volume: 109.9 cm3
Surface Tension: 46.2 dyne/cm
Enthalpy of Vaporization: 56.96 kJ/mol
Vapour Pressure: 0.00291 mmHg at 25 °C 
XLogP3: -1
H-Bond Donor: 2
H-Bond Acceptor: 4
Rotatable Bond Count: 4
Exact Mass: 134.057909
MonoIsotopic Mass: 134.057909
Topological Polar Surface Area: 66.8
Heavy Atom Count: 9
Canonical SMILES: CC(=O)OCC(CO)O
InChI: InChI=1S/C5H10O4/c1-4(7)9-3-5(8)2-6/h5-6,8H,2-3H2,1H3
InChIKey: KMZHZAAOEWVPSE-UHFFFAOYSA-N
EINECS: 247-704-6 
Classification Code: Mutation data

Monoacetin Uses

 Monoacetin (CAS NO.26446-35-5) is used for production of tanning leather and dye. It is also used as a solvent.

Monoacetin Toxicity Data With Reference

1.    

mic-bac-sat 3333 µg/plate

    ENMUDM    Environmental Mutagenesis. 5 (Suppl 1)(1983),3.
2.    

sce-ham-ovr 1500 mg/L

    EMMUEG    Environmental and Molecular Mutagenesis. 13 (1989),60.

Monoacetin Consensus Reports

MONO-ACETIN is reported in EPA TSCA Inventory.

Monoacetin Safety Profile

Risk Statements: 68 
R68:Possible risk of irreversible effects.
Safety Statements: 24/25 
S24/25:Avoid contact with skin and eyes.
RTECS: AK3595000
Mutation data reported. When heated to decomposition it emits acrid smoke and irritating vapors.

Monoacetin Specification

 Monoacetin (CAS NO.26446-35-5) is also named as 1,2,3-Propanetriol, monoacetate ; AI3-24158 ; Acetin ; Acetin, mono- ; Acetoglyceride ; Acetyl monoglyceride ; CCRIS 5881 ; Glycerin monoacetate ; Glycerine monoacetate ; Glycerol acetate ; Glycerol monoacetate ; Glyceryl acetate ; Glyceryl monoacetate ; HSDB 4285 ; Mono-acetin . Monoacetin (CAS NO.26446-35-5) is clear colorless to pale yellow viscous liquid with a characteristic odor. It is very hygroscopic and soluble in water. Monoacetin may hydrolyze in acid or alkaline aqueous solutions. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. They react with oxoacids and carboxylic acids to form esters plus water. Oxidizing agents convert them to aldehydes or ketones. They exhibit both weak acid and weak base behavior. They may initiate the polymerization of isocyanates and epoxides. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Monoacetin is probably combustible.

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