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Name	N-[3-(Trimethoxysilyl)propyl]ethylenediamine	EINECS	217-164-6
CAS No.	1760-24-3	Density	0.975 g/cm³
PSA	65.74000	LogP	0.89410
Solubility	reacts with water	Melting Point	0ºC
Formula	C₈H₂₂N₂O₃Si	Boiling Point	272.2 ºC at 760 mmHg
Molecular Weight	222.36	Flash Point	108.1 ºC
Transport Information	UN 3267 8/PG 2	Appearance	colorless transparent liquid
Safety	26-39-61-37/39-24-36/37/39-23	Risk Codes	38-41-43-52/53-42/43-37/38
Molecular Structure		Hazard Symbols	Xn,Xi
Synonyms	1,2-Ethanediamine,N-[3-(trimethoxysilyl)propyl]- (9CI);(2-Aminoethyl)(3-(trimethoxysilyl)propyl)amine;DynasylanDAMO-T;Geniosil GF 9;N-(Aminoethyl)aminopropyltrimethoxysilane;N-b-Aminoethyl-g-aminopropyyltrimethoxysilane;Prosil 3128;SilaneA 0700;en-APTAS;g-(Ethylenediamino)propyltrimethoxysilane;N-(β-aminoethyl)-γ-aminopropyl]trimethoxysilane;[3-(2-Aminoethyl)Aminopropyl]Trimethoxysilane;	Article Data	17

N-[3-(Trimethoxysilyl)propyl]ethylenediamine Synthetic route

: 107-15-3
ethylenediamine

: 2530-87-2
3-Chloropropyltrimethoxysilan

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

Conditions

Conditions	Yield
Heating;	90%

: 2530-87-2
3-Chloropropyltrimethoxysilan

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

Conditions

Conditions	Yield
In ethylenediamine	70.1%

: 67-56-1
methanol

: C11H28N2O4Si

A: 110-80-5
2-ethoxy-ethanol

B: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

Conditions

Conditions	Yield
at 20℃; Kinetics; Equilibrium constant; Further Variations:; Temperatures;

: 103-72-0
phenyl isothiocyanate

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

: C22H32N4O3S2Si

Conditions

Conditions	Yield
In ethanol for 0.25h; Heating;	100%

: 19494-73-6
1-[(2-oxazepan-1-yl)carbonyl]azepan-2-one

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

A: 105-60-2
caprolactam

B: C15H31N3O5Si

Conditions

Conditions	Yield
In toluene at 75℃; for 3h;	A n/a B 100%

: 30674-80-7
2-Isocyanatoethyl methacrylate

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

: 4,9-dioxo-5-(3-(trimethoxysilyl)propyl)-3,5,8,10-tetraazadodecane-1,12-diyl bis(2-methylacrylate)

Conditions

Conditions	Yield
at 55℃;	100%

: 75-15-0
carbon disulfide

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

: C10H20N2O3S4Si(2-)*2Li(1+)

Conditions

Conditions	Yield
With lithium hydride In tetrahydrofuran for 2h; Heating;	99%

: 2680-03-7
N,N-Dimethylacrylamide

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

: C13H31N3O4Si

Conditions

Conditions	Yield
at 70 - 100℃; for 8.5h;	98%

: 4637-24-5
N,N-dimethyl-formamide dimethyl acetal

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

: 1-[3-(trimethoxysilyl)propyl]-4,5-dihydro-1H-imidazole

Conditions

Conditions	Yield
In toluene at 80℃; for 24h;	98%

: 108-31-6
maleic anhydride

: 5333-84-6
3-methyl-Δ4-tetrahydrophthalic anhydride

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

: C17H32N2O6Si

Conditions

Conditions	Yield
In ethyl acetate at 50 - 60℃;	97%

N-[3-(Trimethoxysilyl)propyl]ethylenediamine Chemical Properties

IUPAC Name: N-(3-Trimethoxysilylpropyl)ethane-1,2-diamine
Molecular Formula: C₈H₂₂N₂O₃Si
Molecular Weight: 222.36 g/mol
SMILES: [Si](CCCNCCN)(OC)(OC)OC
InChI: InChI=1/C8H22N2O3Si/c1-11-14(12-2,13-3)8-4-6-10-7-5-9/h10H,4-9H2,1-3H3
EINECS: 217-164-6
Classification Code: Skin / Eye Irritant
Product Categories: Amino; Amino Silanes (Silane Coupling agents); Functional Materials; Si (Classes of Silicon Compounds); Silane Coupling Agents; Si-O Compounds; Trialkoxysilanes; Adhesion Promoters; Amino Silanes; Coupling Agents; Dispersing Agents; Surface Modifiers; Silane series
Water Solubility: REACTS
Sensitive: Air & Moisture Sensitive
Index of Refraction: 1.441
Molar Refractivity: 60.19 cm³
Molar Volume: 227.9 cm³
Polarizability: 23.86×10^-24 cm³
Surface Tension: 28.2 dyne/cm
Density: 0.975 g/cm³
Flash Point: 108.1 °C
Enthalpy of Vaporization: 51.05 kJ/mol
Boiling Point: 272.2 °C at 760 mmHg
Vapour Pressure of Z 6020 (CAS NO.1760-24-3): 0.00616 mmHg at 25 °C

N-[3-(Trimethoxysilyl)propyl]ethylenediamine Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Source
mouse	LD50	intravenous	180mg/kg (180mg/kg)	U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#03517,
rabbit	LDLo	skin	16mL/kg (16mL/kg)	Union Carbide Data Sheet. Vol. 4/2/1971,
rat	LD50	oral	7460uL/kg (7.46mL/kg)	Union Carbide Data Sheet. Vol. 4/2/1971,

N-[3-(Trimethoxysilyl)propyl]ethylenediamine Consensus Reports

Reported in EPA TSCA Inventory.

N-[3-(Trimethoxysilyl)propyl]ethylenediamine Safety Profile

Poison by intravenous route. Mildly toxic by ingestion and skin contact. A skin and severe eye irritant. When heated to decomposition it emits toxic fumes of NO_x.
Hazard Codes: Harmful Xn,Xi
Risk Statements: 38-41-43-52/53-42/43-37/38
R38:Irritating to skin.
R41:Risk of serious damage to the eyes.
R43:May cause sensitization by skin contact.
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R42/43:May cause sensitization by inhalation and skin contact.
R37/38:Irritating to respiratory system and skin.
Safety Statements: 26-39-61-37/39-24-36/37/39-23
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S39:Wear eye / face protection.
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
S37/39:Wear suitable gloves and eye/face protection.
S24:Avoid contact with skin.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S23:Do not breathe vapour.
RIDADR: UN 3267 8/PG 2
WGK Germany: 3
RTECS: KV7400000
F: 1-10
TSCA: Yes
HazardClass: 8
PackingGroup of Z 6020 (CAS NO.1760-24-3): III

N-[3-(Trimethoxysilyl)propyl]ethylenediamine Specification

Z 6020 (CAS NO.1760-24-3), its Synonyms are AAS-M ; AP 132 ; Dow corning Z-6020 silane ; N-(3-Trimethoxysilylpropyl)-ethylenediamine ; 1,2-Ethanediamine, N-(3-(trimethoxysilyl)propyl)- ; 1,2-Ethanediamine, N1-(3-(trimethoxysilyl)propyl)- ; Ethylenediamine, N-(3-(trimethoxysilyl)propyl)- ; N-(3-(Trimethoxysilyl)propyl)-1,2-ethanediamine ; Silane, (3-(2-aminoethyl)aminopropyl)trimethoxy- . It is colorless transparent liquid.

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