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Basic information

  • Name:
  • Phosphonic acid,P-phenyl-

  • Superlist Name:
  • Phenylphosphonic acid
  • CAS No.:
  • 1571-33-1

  • Molecular Structure:
  • Formula:
  • C6H7O3P
  • Molecular Weight:
  • 158.10
  • Synonyms:
  • Phosphonicacid, phenyl- (6CI,8CI,9CI);Benzenephosphonic acid;Dihydrogenphenylphosphonate;NSC 145;Phenyl phosphonic acid;
  • EINECS:
  • 216-388-1
  • Density:
  • 1.42 g/cm3
  • Melting Point:
  • 162-164 °C(lit.)
  • Boiling Point:
  • 353.7 °C at 760 mmHg
  • Flash Point:
  • 167.7 °C
  • Solubility:
  • water: 40.4 g/100 mL (25 °C)
  • Appearance:
  • white to off-white crystalline powder
  • Hazard Symbols:
  • CorrosiveC,HarmfulXn
  • Risk Codes:
  • 34-37-41-37/38-22-38
  • Safety Description:
  • 26-39-37/39 Details
  • Transport Information:
  • UN 3265 8/PG 2

Famous Chemical Enterprises

  • Livzon
  • Total
  • Shell
  • Dupont
  • Exxonmobil
  • Akzonobel
  • Basf
  • Bayer
  • BP

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Chemistry

The Molecular formula of PHENYLPHOSPHONIC ACID(1571-33-1):C6H7O3P  
The Molecular Weight of PHENYLPHOSPHONIC ACID(1571-33-1):158.09 
The Molecular Structure of PHENYLPHOSPHONIC ACID(1571-33-1) is:
Density:1.42 g/cm3
Melting point:162-164 °C(lit.)
Boiling point:353.7 °C at 760 mmHg
Flash point:167.7 °C     
Solubility in water:40.4 g/100 mL (25 oC)
BRN:2245168
Index of Refraction:1.571  
Molar Refractivity:36.55 cm3  
Molar Volume:111.1 cm3
Polarizability:14.49 10-24cm3 
Surface Tension:59.7 dyne/cm
Enthalpy of Vaporization:63.17 kJ/mol  
Vapour Pressure:1.3E-05 mmHg at 25°C  
Appearance:white to off-white crystalline powder  
IUPAC Name:phenylphosphonic acid
Synonyms:Benzolphosphonsαure;Dihydrogenphenylphosphonate;phenyl-phosphonicaci;Phosphonicacid,phenyl-;PPOA;PHOSPHORIC ACID PHENYL ESTER DICHLORIDE;PHENYLPHOSPHONIC ACID;PHENYL PHOSPHODICHLORIDATE

Uses

A large number of benzene phosphonic acid compounds are used in pesticide production and use of newly developed anti-fouling paints as intermediates for the manufacture of smoldering agent, catalyst and so on.
 

Production

It is obtained by the hydrolysis of benzene dichloride.

Toxicity Data With Reference

1.   

ipr-mus LD50:110 mg/kg

   CBCCT*    “Summary Tables of Biological Tests“ National Research Council Chemical-Biological Coordination Center. 2 (1950),55.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by intraperitoneal route. When heated to decomposition it emits toxic fumes of POx.
Hazard Codes:C,Xn
C:Corrosive
Xn:Harmful
Risk Statements
R34:Causes burns.
R37:Irritating to the respiratory system.
R41:Risk of serious damage to eyes.
R37/38:Irritating to respiratory system and skin .
R22:Harmful if swallowed.
R38:Irritating to the skin.
Safety Statements
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S39:Wear eye/face protection .
S37/39:Wear suitable gloves and eye/face protection .
RIDADR:UN 3265 8/PG 2
WGK Germany:3
RTECS:TD4393000
F:10
HazardClass:8
PackingGroup:III

Specification

Chemical Stability: Stable under normal temperatures and pressures. 
Conditions to Avoid: Incompatible materials, temperatures above 200°C. 
Incompatibilities with Other Materials: Strong oxidizing agents, bases. 
Hazardous Polymerization: Will not occur. 
Hazardous Decomposition Products: Phosphine, carbon monoxide, oxides of phosphorus, carbon dioxide, benzene. 
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