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Phenoxytrimethylsilane

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Name

Phenoxytrimethylsilane

EINECS 216-211-8
CAS No. 1529-17-5 Density 0.913 g/cm3
PSA 9.23000 LogP 2.90030
Solubility N/A Melting Point -55 °C
Formula C9H14OSi Boiling Point 163.71 °C at 760 mmHg
Molecular Weight 166.295 Flash Point 42.756 °C
Transport Information N/A Appearance Clear colorless liquid
Safety 26-36 Risk Codes 10-36/37/38
Molecular Structure Molecular Structure of 1529-17-5 (PHENOXYTRIMETHYLSILANE) Hazard Symbols IrritantXi
Synonyms

Silane,trimethylphenoxy- (6CI,7CI,8CI,9CI);(Trimethylsiloxy)benzene;Phenol trimethylsilyl ether;Phenoxytrimethylsilane;Phenyl trimethylsilyl ether;Trimethylphenoxysilane;Trimethylsiliconphenoxide;Trimethylsilyl phenyl ether;

Article Data 198

Phenoxytrimethylsilane Specification

The Benzene,[(trimethylsilyl)oxy]- is an organic compound with the formula C9H14OSi. The IUPAC name of this chemical is Trimethyl(phenoxy)silane. With the CAS registry number 1529-17-5, it is also named as Phenoxy(trimethyl)silane. Besides, it is clear colorless liquid, which should be stored in a dry, well-ventilated, lightproof place.

Physical properties about Benzene,[(trimethylsilyl)oxy]- are: (1)ACD/BCF (pH 5.5): 1; (2)ACD/BCF (pH 7.4): 1; (3)ACD/KOC (pH 5.5): 12.87; (4)ACD/KOC (pH 7.4): 12.87; (5)#H bond acceptors: 1; (6)#Freely Rotating Bonds: 2; (7)Polar Surface Area: 9.23 Å2; (8)Index of Refraction: 1.471; (9)Molar Refractivity: 50.914 cm3; (10)Molar Volume: 182.186 cm3; (11)Polarizability: 20.184×10-24 cm3; (12)Surface Tension: 23.864 dyne/cm; (13)Density: 0.913 g/cm3; (14)Flash Point: 42.756 °C; (15)Enthalpy of Vaporization: 38.378 kJ/mol; (16)Boiling Point: 163.71 °C at 760 mmHg; (17)Vapour Pressure: 2.668 mmHg at 25 °C. 

Preparation: this chemical can be prepared by phenol. This reaction will need reagent triethylamine. The reaction time is 1 hour with reaction temperature of -40 °C. The yield is about 47%.

Uses of Benzene,[(trimethylsilyl)oxy]-: it can be used to produce Isobutyric acid phenyl ester. It will need reagents TiCl4, AgOTf, p-Trifluoromethylbenzoic anhydride and solvent CH2Cl2 with reaction time of 6 hours. The yield is about 77%.

When you are using this chemical, please be cautious about it as the following:
It is flammable. Besides, this chemical is irritating to eyes, respiratory system and skin. When you are using it, wear suitable protective clothing. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)InChI: InChI=1/C9H14OSi/c1-11(2,3)10-9-7-5-4-6-8-9/h4-8H,1-3H3
(2)InChIKey: OJAJJFGMKAZGRZ-UHFFFAOYAW
(3)Std. InChI: InChI=1S/C9H14OSi/c1-11(2,3)10-9-7-5-4-6-8-9/h4-8H,1-3H3
(4)Std. InChIKey: OJAJJFGMKAZGRZ-UHFFFAOYSA-N

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