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Potassium Azide

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Name

Potassium Azide

EINECS 244-013-1
CAS No. 20762-60-1 Density 2.040
PSA 49.75000 LogP 0.21376
Solubility g/100g H2O: 41.4 (0°C), 50.8 (20°C), 61.0 (40°C), 106 (100°C) [LAN05] Melting Point 350oC
Formula KN3 Boiling Point N/A
Molecular Weight 81.1184 Flash Point N/A
Transport Information N/A Appearance N/A
Safety A poison by ingestion. Hydrolysis yields KOH which is toxic and irritating. When heated it explodes weakly releasing nitrogen. Explosive reaction with sulfur dioxide at 120°C. Reacts with carbon disulfide to form an explosive product. Reacts violently with manganese dioxide when warmed. When heated to decomposition it emits very toxic fumes of NOx and K2O. See also AZIDES. Risk Codes 25
Molecular Structure Molecular Structure of 20762-60-1 (potassium azide) Hazard Symbols T
Synonyms

Potassiumazide (6CI,8CI); PPG 101

Article Data 43

Potassium Azide Chemical Properties

Molecular Structure:

Molecular Formula: KN3
Molecular Weight: 81.1184
IUPAC Name: Potassium Azide
Synonyms of Potassium Azide (CAS NO.20762-60-1): AI3-52879 ; Caswell No. 682B ; EINECS 244-013-1 ; EPA Pesticide Chemical Code 107702 ; Potassium azide (K(N3))
CAS NO: 20762-60-1

Potassium Azide Uses

  Potassium Azide (CAS NO.20762-60-1) has been found to act as a nitrification inhibitor in soil.

Potassium Azide Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
bird - wild LD50 oral 17800ug/kg (17.8mg/kg)   Archives of Environmental Contamination and Toxicology. Vol. 12, Pg. 355, 1983.
rat LD50 oral 27mg/kg (27mg/kg)   National Technical Information Service. Vol. PB85-143766,

Potassium Azide Safety Profile

A poison by ingestion. Hydrolysis yields KOH which is toxic and irritating. When heated it explodes weakly releasing nitrogen. Explosive reaction with sulfur dioxide at 120°C. Reacts with carbon disulfide to form an explosive product. Reacts violently with manganese dioxide when warmed. When heated to decomposition it emits very toxic fumes of NOx and K2O. See also AZIDES
RIDADR of Potassium Azide (CAS NO.20762-60-1): 2811
HazardClass: 6.1(a)
PackingGroup: II

Potassium Azide Specification

  Potassium Azide (CAS NO.20762-60-1) is a colorless crystals. It is a salt of hydrazoic acid, and crystallizes in a tetragonal structure. Upon heating or irradiation with ultraviolet light, it decomposes into potassium metal and nitrogen gas. Unlike heavy-metal azides, it is not sensitive to shock, but may explode if heated rapidly.

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