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Ppropyl ether

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Ppropyl ether

EINECS 203-869-6
CAS No. 111-43-3 Density 0.7360g/cm3
PSA 9.23000 LogP 1.82300
Solubility slightly soluble in Water Melting Point -122ºC
Formula C6H14 O Boiling Point 89-91 ºC
Molecular Weight 102.177 Flash Point -20 deg C ( -4.00 deg F)
Transport Information UN2384 Appearance clear, colorless Liquid
Safety Poison by intravenous route. Moderately toxic by inhalation. Possibly narcotic. A flammable liquid and dangerous fire hazard when exposed to heat, flame, or oxidizers. Forms explosive peroxides. Dangerous upon exposure to heat or flame; can react vigorously with oxidizing materials. When heated to decomposition it emits acrid smoke and irritating fumes. See also ETHERS. Risk Codes 11 19 66 67
Molecular Structure Molecular Structure of 111-43-3 (n-Propyl ether) Hazard Symbols FlammableF
Synonyms

Propylether (6CI,8CI); 1,1'-Oxybis[propane]; 4-Oxaheptane; Di-n-propyl ether;Dipropyl ether; Dipropyl oxide; n-Propyl ether

Article Data 101

Ppropyl ether Chemical Properties

MF: C6H14O
MW: 102.17
Flash Point: 4.4 °C
EINECS: 203-869-6 
Melting Point: -123 °C
Storage temp  Flammables area
IUPAC Name: 1-propoxypropane
Enthalpy of Vaporization: 31.31 kJ/mol 
Vapour Pressure: 64.2 mmHg at 25°C
Boiling Point: 90.2 °C at 760 mmHg
Density: 0.736 g/mL at 25 °C(lit.)
Vapor pressure: 55 mm Hg ( 20 °C)
Refractive index: n20/D 1.380(lit.)
Chemical Properties: Clear colorless liquid
Synonyms: Dipropyl ether ; Di-n-propplether ; Di-n-propyl ether ; Propyl ether ; N-propyl ether ; (N-C3H7)2O ; 1,1’-Oxybis-propan ; 1,1’-Oxybispropane
Following is the molecular structure of Propyl ether (111-43-3):

Ppropyl ether Production

 Reactivity Profile: Ethers, such as Dipropyl ether (111-43-3), can act as bases. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert.

Ppropyl ether Toxicity Data With Reference

1.    

ihl-mus LC50:163 mg/m3/15M

    ANESAV    Anesthesiology. 11 (1950),455.
2.    

ivn-mus LD50:204 mg/kg

    JPMSAE    Journal of Pharmaceutical Sciences. 67 (1978),566.

Ppropyl ether Consensus Reports

Reported in EPA TSCA Inventory.

Ppropyl ether Safety Profile

Poison by intravenous route. Moderately toxic by inhalation. Possibly narcotic. A flammable liquid and dangerous fire hazard when exposed to heat, flame, or oxidizers. Forms explosive peroxides. Dangerous upon exposure to heat or flame; can react vigorously with oxidizing materials. When heated to decomposition it emits acrid smoke and irritating fumes.
Safety Information of Propyl ether (111-43-3):
Hazard Codes: F
F: Highly Flammable
Risk Statements: 11-19-66-67
11: Highly Flammable 
19: May form explosive peroxides 
66: Repeated exposure may cause skin dryness or cracking 
67: Vapors may cause drowsiness and dizziness  
Safety Statements: 9-16-29-33
9: Keep container in a well-ventilated place 
16: Keep away from sources of ignition - No smoking 
29: Do not empty into drains 
33: Take precautionary measures against static discharges 
RIDADR: UN 2384 3/PG 2
WGK Germany: 1
RTECS: UJ5125000
HazardClass: 3
PackingGroup: II

Ppropyl ether Standards and Recommendations

DOT Classification:  3; Label: Flammable Liquid

Ppropyl ether Specification

Health Hazard and Fire Hazard of Propyl ether (111-43-3):
Health Hazard: Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control may cause pollution.
Fire Hazard: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

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