Ethanaminium, N,N,N-triethyl-, benzenethiolate

Base Information

• Chemical Name: Ethanaminium, N,N,N-triethyl-, benzenethiolate
• CAS No.: 3193-72-4
• Molecular Formula: C8H20N.C6H5S
• Molecular Weight: 239.425
• Mol file: 3193-72-4.mol

Synonyms:

Chemical Property of Ethanaminium, N,N,N-triethyl-, benzenethiolate

Chemical Property:

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Ethanaminium, N,N,N-triethyl-, benzenethiolate

There total 1 articles about Ethanaminium, N,N,N-triethyl-, benzenethiolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

tetraethylammonium hydroxide (77-98-5) + thiophenol (108-98-5) → tetraethylammonium phenylthiolate (3193-72-4)

Guidance literature:

In methanol; at 20 ℃; for 0.5h;

DOI:10.1021/acs.joc.8b00143

Reference yield: 95.1%

tungsten hexacarbonyl (14040-11-0) + tetraethylammonium phenylthiolate (3193-72-4) → {(C2H5)4N}(1+)*{W(CO)5(S(C6H5))}(1-) = {(C2H5)4N}{W(CO)5(S(C6H5))} (116148-13-1)

Guidance literature:

With THF; In tetrahydrofuran; Irradiation (UV/VIS); N2 atmosphere; addn. of soln. of W(CO)5*THF in THF (prepd. form photolysis of W(CO)6 in THF) to org. compd., stirring (15 min); pptn. on addn. of hexane, recrystn. (THF/hexane);

Reference yield: 94.2%

tetraethylammonium phenylthiolate (3193-72-4) + molybdenum hexacarbonyl (13939-06-5,199620-15-0) → {(C2H5)4N}(1+)*{Mo(CO)5(S(C6H5))}(1-) = {(C2H5)4N}{Mo(CO)5(S(C6H5))} (116148-75-5)

Guidance literature:

In tetrahydrofuran; N2 atmosphere; addn. of Mo(CO)6 to org. compd. (N2 stream), addn. of THF, stirring (48 h); filt., washing ppt. with THF, combining soln., pptn. on concn. and addn. of hexane, recrystn. (THF/ diethyl ether/ hexane); IR monitoring;

upstream raw materials:

tetraethylammonium hydroxide

thiophenol

Downstream raw materials:

(Et₄N){Fe(salen)(PhS)}

{Et4N}2{Mo2(CO)8(μ-SPh)2}

{(C₂H₅)4N}⁽¹⁺⁾*{Mo(CO)5(S(C₆H₅))}^(1-) = {(C₂H₅)4N}{Mo(CO)5(S(C₆H₅))}

[Fe₄S₄(benzenethiolate)4]^(2-)

Refernces