Carbonofluoridic acid, phenyl ester

Base Information

• Chemical Name: Carbonofluoridic acid, phenyl ester
• CAS No.: 351-80-4
• Molecular Formula: C7H5FO2
• Molecular Weight: 140.114
• Mol file: 351-80-4.mol

Synonyms:

Chemical Property of Carbonofluoridic acid, phenyl ester

Chemical Property:

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Carbonofluoridic acid, phenyl ester

There total 9 articles about Carbonofluoridic acid, phenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.5%

[1,3]-dioxolan-2-one (96-49-1) + phenyl chloroformate (1885-14-9) → phenyl fluoroformate (351-80-4)

Guidance literature:

With potassium fluoride;

Reference yield: 85.0%

phenyl chloroformate (1885-14-9) → phenyl fluoroformate (351-80-4)

Guidance literature:

With sodium fluoride; 15-crown-5; In acetonitrile; at 20 - 40 ℃; for 16h;

Reference yield: 70.0%

phenyl-α-chloroethyl-carbonate (50972-20-8) → phenyl fluoroformate (351-80-4)

Guidance literature:

With potassium fluoride; 18-crown-6 ether; at 75 ℃; for 1.5h; under 20 Torr;

DOI:10.1021/jo00293a032

upstream raw materials:

1-trifluoromethoxybenzene

phenyl-α-chloroethyl-carbonate

phenyl chloroformate

benzene

Downstream raw materials:

ethyl phenyl carbonate

Carbonic acid phenyl ester 2,2,2-trichloro-1-fluoro-ethyl ester

vinyl phenyl carbonate

Isopropenyl-phenylcarbonat

Refernces

• 1、 -. "Synthesis of vinyl carbonates for use in producing vinyl carbamates". Example 1. . Retrieved 2008/06/13.
• 2、 Suyama, T.,Kato, S.,Mizutani, Y.. "Preparations of carboxylic acid esters containing heptafluoroisopropyl groups". . p. 93 - 99. Retrieved 2007/10/02.