Titanium(4+) tetrafluoride

Base Information

• Chemical Name: Titanium(4+) tetrafluoride
• CAS No.: 7783-63-3
• Molecular Formula: F4Ti
• Molecular Weight: 123.874
• Hs Code.: 28261990
• UNII: T08RW8YRG1
• Nikkaji Number: J95.272I
• Mol file: 7783-63-3.mol

Synonyms:Titanium fluoride (TiF4), (T-4)-;F4Ti;F4-Ti;Titanium fluoride (TiF4);titanium(4+) tetrafluoride;TITANIUM(4+) FLUORIDE;TITANIUM TETRAFLUORIDE [MI];AKOS015833203;A839227

Chemical Property of Titanium(4+) tetrafluoride

Chemical Property:

• Appearance/Colour: white powder
• Melting Point: >400ºC
• Boiling Point: 284ºC
• PSA: 0.00000
• Density: 2.798g/cm³
• LogP: 1.68080
• Sensitive.: Moisture Sensitive
• Water Solubility.: Insoluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 123.9415533
• Heavy Atom Count: 5
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Titanium(IV) fluoride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 20/21/22-34
• Safety Statements: 26-27-28-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [F-].[F-].[F-].[F-].[Ti+4]
• Uses: Titanium tetrafluoride is used for preparation of glycosyl fluorides2; glycosylation3; preparation of fluorohydrins4; addition of carbanions to aldehydes and imines.5 Titanium(IV) fluoride is used for preparation of glycosyl fluorides, glycosylation, preparation of fluorohydrins, addition of carbanions to aldehydes and imines. It is a catalyst for chemoselective synthesis and deprotection of geminal diacetates of aldehydes. Catalyst for:Chemoselective synthesis and deprotection of geminal diacetates of aldehydes

Technology Process of Titanium(4+) tetrafluoride

There total 43 articles about Titanium(4+) tetrafluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chloryl fluoride (13637-83-7) + titanium tetrachloride (7550-45-0) → 2ClO2(1+)*TiF6(2-)=(ClO2)2TiF6 + chlorine dioxide (10049-04-4,25052-55-5) + chlorine (7782-50-5) + titanium(IV) fluoride (7783-63-3)

Guidance literature:

In neat (no solvent); at -100°C;;

Reference yield:

uranium hexafluoride (7783-81-5) + titanium tetrachloride (7550-45-0) → uranium(IV) tetrafluoride (10049-14-6) + titanium(IV) fluoride (7783-63-3)

Guidance literature:

byproducts: Cl2; UF6 in excess;

Reference yield:

uranium hexafluoride (7783-81-5) + titanium tetrachloride (7550-45-0) → uranium hexachloride (13763-23-0) + uranium(IV) tetrafluoride (10049-14-6) + titanium(IV) fluoride (7783-63-3)

Guidance literature:

byproducts: Cl2; TiCl4 in excess;

upstream raw materials:

titanium

chlorine trifluoride

hydrogen fluoride

titanium tetrachloride

Downstream raw materials:

2,3,4,6-tetra-O-acetyl-α-D-galactopyranosyl fluoride

titanium

titanium(III) fluoride

trifluorophosphoric acid

Refernces

• 1、 Shlyapnikov, Igor M.,Goreshnik, Evgeny A.,Mazej, Zoran. "Guanidinium Perfluoridotitanate(IV) Compounds: Structural Determination of an Oligomeric [Ti6F27]3– Anion, and an Example of a Mixed-Anion Salt Containing Two Different Fluoridotitanate(IV) Anions". . p. 5246 - 5257. Retrieved 2018.
• 2、 Shlyapnikov, Igor M.,Mercier, Helene P. A.,Goreshnik, Evgeny A.,Schrobilgen, Gary J.,Mazej, Zoran. "Crystal structures and raman spectra of imidazolium poly[perfluorotitanate(IV)] salts containing the [TiF6]2-, ([Ti2F9]-)∞, and [Ti 2F11]3- and the New [Ti4F 20]4- and [Ti5F23]3- anions". . p. 8315 - 8326. Retrieved 2013.
• 3、 Shlyapnikov, Igor M.,Goreshnik, Evgeny A.,Mazej, Zoran. "Syntheses and the crystal chemistry of the perfluoridotitanate(IV) compounds templated with ethylenediamine and melamine". . p. 255 - 262. Retrieved 2019.
• 4、 Louvain,Karkar,El-Ghozzi,Bonnet,Guerin,Willmann. "Fluorination of anatase TiO2 towards titanium oxyfluoride TiOF2: A novel synthesis approach and proof of the Li-insertion mechanism". . p. 15308 - 15315. Retrieved 2014.