(E)-5-Undecene

Base Information

• Chemical Name: (E)-5-Undecene
• CAS No.: 764-97-6
• Molecular Formula: C11H22
• Molecular Weight: 154.296
• UNII: O41NLB9Z1L
• DSSTox Substance ID: DTXSID00874001
• Nikkaji Number: J97.383A,J97.384J
• Wikidata: Q27160456
• Mol file: 764-97-6.mol

Synonyms:(E)-5-Undecene;5-Undecene, (E)-;(E)-undec-5-ene;5-Undecene, (5E)-;5-Undecene;764-97-6;trans-5-Undecene;(5E)-5-Undecene;UNII-O41NLB9Z1L;O41NLB9Z1L;4941-53-1;trans-undec-5-ene;5-Undecene, trans-;(5E)-5-Undecene #;.EPSILON.-TRANS-UNDECENE;CHEBI:88565;DTXSID00874001;NGCRXXLKJAAUQQ-PKNBQFBNSA-N;Q27160456

Chemical Property of (E)-5-Undecene

Chemical Property:

• Melting Point: -61.1°C
• Refractive Index: 1.4285
• Boiling Point: 187.71°C (estimate)
• PSA: 0.00000
• Density: 0.7497
• LogP: 4.31310
• XLogP3: 5.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 7
• Exact Mass: 154.172150702
• Heavy Atom Count: 11
• Complexity: 82

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Classes -> Aliphatics, Unsaturated
• Canonical SMILES: CCCCCC=CCCCC
• Isomeric SMILES: CCCCC/C=C/CCCC

Technology Process of (E)-5-Undecene

There total 11 articles about (E)-5-Undecene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

6-undecanol (23708-56-7) + benzoic acid (65-85-0,8013-63-6) → 5-undecene (4941-53-1,764-96-5,764-97-6) + undec-6-yl benzoate (1051938-75-0)

Guidance literature:

With toluene-4-sulfonic acid; at 100 ℃; for 50h;

DOI:10.1016/j.tetlet.2008.06.058

Reference yield: 89.0%

6-undecanol (23708-56-7) + phenylpropyolic acid (637-44-5) → undec-6-yl phenylpropiolate + 5-undecene (4941-53-1,764-96-5,764-97-6)

Guidance literature:

With dimesitylammonium pentafluorobenzenesulfonate; In n-heptane; at 80 ℃; for 48h;

DOI:10.1021/ja050223v

Reference yield: 83.0%

6-undecanol (23708-56-7) + 4-Phenylbutyric acid (1821-12-1) → undec-6-yl 4-phenylbutyrate + 5-undecene (4941-53-1,764-96-5,764-97-6)

Guidance literature:

With N-(2,6-diisopropylphenyl)-N-(2,4,6-mesityl)ammonium pentafluorobenzenesulfonate; In hexane; at 70 ℃; for 23h;

DOI:10.1016/j.tet.2005.09.059

upstream raw materials:

6-undecanol

4-Phenylbutyric acid

phenylpropyolic acid

benzoic acid

Downstream raw materials:

α-n-pentylheptanoic acid

2-butyloctanoic acid

n-Undecane

Refernces

• 1、 Thiam, Zeynabou,Abou-Hamad, Edy,Dereli, Busra,Liu, Lingmei,Emwas, Abdul-Hamid,Ahmad, Rafia,Jiang, Hao,Isah, Abdulrahman Adamu,Ndiaye, Papa Birame,Taoufik, Mostafa,Han, Yu,Cavallo, Luigi,Basset, Jean-Marie,Eddaoudi, Mohamed. "Extension of surface organometallic chemistry to metal?organic frameworks: Development of a well-defined single site [(≡Zr? O?)W(=O)(CH2TBu)3] olefin metathesis catalyst". supporting information. p. 16690 - 16703. Retrieved 2020/11/09.
• 2、 Carenco, Sophie,Leyva-Pérez, Antonio,Concepción, Patricia,Boissire, Cédric,Mézailles, Nicolas,Sanchez, Clément,Corma, Avelino. "Nickel phosphide nanocatalysts for the chemoselective hydrogenation of alkynes". experimental part. p. 21 - 28. Retrieved 2012/07/27.