Phosphine selenide, tris(4-methoxyphenyl)-

Base Information

• Chemical Name: Phosphine selenide, tris(4-methoxyphenyl)-
• CAS No.: 41398-48-5
• Molecular Formula: C21H21O3PSe
• Molecular Weight: 431.32300
• Mol file: 41398-48-5.mol

Synonyms:(p-MeOC6H4)3PSe;tris(p-methoxyphenyl)phosphine selenide;tris(4-methoxyphenyl)phosphine selenide;Tris(p-methoxyphenyl) selenide;

Chemical Property of Phosphine selenide, tris(4-methoxyphenyl)-

Chemical Property:

• Boiling Point: 536.7±60.0 °C(Predicted)
• PSA: 37.50000
• LogP: 3.20230

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Phosphine selenide, tris(4-methoxyphenyl)-

There total 1 articles about Phosphine selenide, tris(4-methoxyphenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

P(p-CH3OC6H4)3 (855-38-9) → tris(p-methoxyphenyl)phosphine selenide (41398-48-5)

Guidance literature:

In isopropyl alcohol; Heating;

Reference yield: 35.0%

dodecacarbonyl-triangulo-triruthenium (15243-33-1) + tris(p-methoxyphenyl)phosphine selenide (41398-48-5) → [Ru3(μ3-Se)2(CO)8(P(p-C6H4OMe)3)] + [Ru3(μ3-Se)2(CO)7(P(p-C6H4OMe)3)2] + [Ru3(μ3-Se)(μ3-CO)(CO)7(P(C6H4OCH3)3)2]

Guidance literature:

With Me₃NO; In toluene; under N2, Schlenk tube; mixt. was stirred for 1.5 h at 70°C; soln. was evapd. to dryness, residue was dissolved in CH2Cl2, chromd., extd. with CH2Cl2, recrystd. with MeOH-CH2Cl2; elem. anal.;

DOI:10.1039/b203004g

Reference yield:

[Ru3(μ3-Se)(μ3-CO)(CO)7(P(C6H4OCH3)3)2] + tris(p-methoxyphenyl)phosphine selenide (41398-48-5) → [Ru3(μ3-Se)2(CO)7(P(p-C6H4OMe)3)2]

Guidance literature:

With Me₃NO; In toluene; under N2, Schlenk tube; mixt. was stirred at 70°C; IR monitoring;

DOI:10.1039/b203004g

upstream raw materials:

P(p-CH₃OC₆H₄)3

Refernces