4-Ethoxyphenylmagnesium bromide

Base Information

• Chemical Name: 4-Ethoxyphenylmagnesium bromide
• CAS No.: 41842-30-2
• Molecular Formula: C8H9BrMgO
• Molecular Weight: 225.368
• Hs Code.: 2931900090
• European Community (EC) Number: 689-679-8
• Mol file: 41842-30-2.mol

Synonyms:4-ETHOXYPHENYLMAGNESIUM BROMIDE;41842-30-2;MFCD08741509;4-Ethoxyphenylmagnesium bromide, 0.50 M in 2-MeTHF;p-ethoxyphenylmagnesium bromide;SCHEMBL1551402;4-ethoxyphenyl magnesium bromide;LSLTUAIHOGSOKB-UHFFFAOYSA-M;AKOS016017727;4-Ethoxyphenylmagnesium bromide, 0.50 M in THF;4-Ethoxyphenylmagnesium bromide 0.5 M in Tetrahydrofuran;4-Ethoxyphenylmagnesium bromide, 0.5M in tetrahydrofuran

Chemical Property of 4-Ethoxyphenylmagnesium bromide

Chemical Property:

• Flash Point: -17℃
• PSA: 9.23000
• Density: 1.004 g/mL at 25 °C
• LogP: 2.73110
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 2
• Exact Mass: 223.96872
• Heavy Atom Count: 11
• Complexity: 157

Purity/Quality:

97% ^*data from raw suppliers

4-Ethoxyphenylmagnesium bromide solution 1M in THF ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,C
• Statements: 11-14-19-34-37-40
• Safety Statements: 16-26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCOC1=CC=[C-]C=C1.[Mg+2].[Br-]

Technology Process of 4-Ethoxyphenylmagnesium bromide

There total 3 articles about 4-Ethoxyphenylmagnesium bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-bromoethoxybenzene (588-96-5) → 4-ethoxyphenylmagnesium bromide (41842-30-2)

Guidance literature:

With magnesium; In tetrahydrofuran;

Reference yield:

4-bromo-phenol (106-41-2) → 4-ethoxyphenylmagnesium bromide (41842-30-2)

Guidance literature:

Multi-step reaction with 2 steps

1: 91 percent / anhydrous potassium carbonate / butan-2-one / Heating

2: magnesium turnings / tetrahydrofuran

With potassium carbonate; magnesium; In tetrahydrofuran; butanone;

Reference yield:

4-bromoethoxybenzene (588-96-5) → 4-ethoxyphenylmagnesium bromide (41842-30-2)

Guidance literature:

With diethyl ether; iodine;

upstream raw materials:

4-bromoethoxybenzene

4-bromo-phenol

Downstream raw materials:

(4-ethoxy-phenyl)-phenyl-[2]pyridyl-methanol

2,3-bis(4-ethoxyphenyl)-1H-inden-1-one

Bis-(4-ethoxy-phenyl)-hydroxy-acetic acid N'-[1-(4-ethoxy-phenyl)-ethyl]-hydrazide

2,2-Bis-(4-ethoxy-phenyl)-1-phenyl-ethanone

Refernces

• 1、 Chan, L. K. M.,Gray, G. W.,Lacey, D.,Toyne, K. J.. "Synthesis and Liquid Crystal Behaviour of Further 4,4"-Disubstituted 2'-Fluoro-1,1':4',1"-Terphenyls". . p. 209 - 240. Retrieved 2007/10/02.