N,N'-DIBENZYLSULFAMIDE

Base Information

• Chemical Name: N,N'-DIBENZYLSULFAMIDE
• CAS No.: 42731-71-5
• Molecular Formula: C14H16N2O2S
• Molecular Weight: 276.359
• Mol file: 42731-71-5.mol

Synonyms:

Chemical Property of N,N'-DIBENZYLSULFAMIDE

Chemical Property:

Purity/Quality:

N,N'-DIBENZYLSULFAMIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N'-DIBENZYLSULFAMIDE

There total 8 articles about N,N'-DIBENZYLSULFAMIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

benzylamine (100-46-9) → N,N'-dibenzylsulfamide (42731-71-5)

Guidance literature:

With SULFAMIDE; for 0.133333h; Reflux; Microwave irradiation; Green chemistry;

DOI:10.1080/10426507.2013.819868

Reference yield: 91.0%

2-hydroxyphenyl N-benzylsulfamate (74282-81-8) + benzylamine (100-46-9) → N,N'-dibenzylsulfamide (42731-71-5)

Guidance literature:

In 1,4-dioxane; for 2h; Heating;

DOI:10.1021/jo01314a034

Reference yield: 69.0%

2,6-dibenzyl-2,3,5,6-tetrahydro-4-hydroximino-3,5-dioxo-1,2,6-thiadiazine 1,1-dioxide (106350-09-8) → N,N'-dibenzylsulfamide (42731-71-5)

Guidance literature:

With hydrogenchloride; In ethanol; water; for 1h; Heating;

upstream raw materials:

phenylchlorosulfate

benzylamine

2,6-dibenzyl-2,3,5,6-tetrahydro-4-hydroximino-3,5-dioxo-1,2,6-thiadiazine 1,1-dioxide

2-hydroxyphenyl N-benzylsulfamate

Downstream raw materials:

1,3-dibenzyl-1H,3H-2,1,3-benzothiadiazole 2,2-dioxide

C₂₆H₂₆N₂O₄S

N,1-Bis-(phenylmethyl)-2-(phenylmethylen)-hydrazinsulfonamid

2,6-dibenzyl-(2,3,5,6-tetrahydro)-1,2,6-thiadiazin-3,5-dione 1,1-dioxide

Refernces

• 1、 Dehamchia, Mohamed,Ichrak, Bouguessa,Rega?nia, Zine. "The Zeolite ZSM-5-SO3H as an Effcient Mild Heterogeneous Catalyst for the Synthesis of 1,2,5-Thiadiazolidines, 1,2,6-Thiadiazines, and Benzo[d][1,2,7] thiadiazepines Under Microwave-assisted Solvent-free Conditions". . p. 509 - 514. Retrieved 2021/02/02.
• 2、 Li, Lu,Qiu, Dachuan,Shi, Jiarong,Li, Yang. "Vicinal Diamination of Arenes with Domino Aryne Precursors". supporting information. p. 3726 - 3729. Retrieved 2016/08/16.