Phosphine, diphenyl-, sodium salt

Base Information

• Chemical Name: Phosphine, diphenyl-, sodium salt
• CAS No.: 4376-01-6
• Molecular Formula: C12H11P.Na
• Molecular Weight: 208.175
• Mol file: 4376-01-6.mol

Synonyms:

Chemical Property of Phosphine, diphenyl-, sodium salt

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Phosphine, diphenyl-, sodium salt

There total 19 articles about Phosphine, diphenyl-, sodium salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.8%

triphenylphosphine (603-35-0) → sodium diphenylphosphide (4376-01-6)

Guidance literature:

With sodium; Nytro 10GBN; In tetrahydrofuran; at 45 - 55 ℃; Product distribution / selectivity; Inert atmosphere;

Reference yield: 87.0%

diphenylphosphane (829-85-6) → sodium diphenylphosphide (4376-01-6)

Guidance literature:

With sodium hydride; In tetrahydrofuran; Sealed tube; Inert atmosphere;

DOI:10.1016/j.chempr.2020.04.008

Reference yield: 36.0%

benzyldiphenylphosphane (7650-91-1) → C13H12P(1-)*Na(1+) (120011-44-1) + sodium diphenylphosphide (4376-01-6)

Guidance literature:

With sodium; In tetrahydrofuran; at 25 ℃; for 1h; Inert atmosphere;

DOI:10.1021/acs.organomet.0c00295

upstream raw materials:

P(p-CH₃OC₆H₄)3

Tetraphenyldiphosphin

diphenylphosphane

chloro-diphenylphosphine

Downstream raw materials:

Pentafluorpropionyl-diphenylphosphin

1-(diphenylphosphanyl)ethan-1-one

2-(diphenylphosphino)pyridine

4-(diphenylphosphino)pyridine

Refernces

• 1、 Artyushin, Oleg I.,Brel, Valery K.,Karandashev, Vasilii K.,Turanov, Aleksandr N.,Vologzhanina, Anna V.. "Synthesis, coordination and extraction properties of 2,3-bis(diphenylphosphoryl)pyridine toward f-block elements". . p. 306 - 308. Retrieved 2021.
• 2、 Murshid, Nimer,El-Temtamy, Abdelrahman,Wang, Xiaosong. "Synthesis and solution behaviour of metal-carbonyl amphiphiles with an Fp (CpFe(CO)2) junction". . p. 40 - 45. Retrieved 2017.
• 3、 Zhang, Jian-Qiu,Han, Li-Biao. "Reductive conversion of phosphoryl P(O) compounds to trivalent organophosphines R3P". . . Retrieved 2021/02/20.
• 4、 Ye, Jingjing,Zhang, Jian-Qiu,Saga, Yuta,Onozawa, Shunya,Kobayashi, Shu,Sato, Kazuhiko,Fukaya, Norihisa,Han, Li-Biao. "Ready Approach to Organophosphines from ArCl via Selective Cleavage of C-P Bonds by Sodium". supporting information. p. 2682 - 2694. Retrieved 2020/07/30.