benzyldibutylamine

Base Information

• Chemical Name: benzyldibutylamine
• CAS No.: 4383-27-1
• Molecular Formula: C15H25N
• Molecular Weight: 219.37
• Mol file: 4383-27-1.mol

Synonyms:

Chemical Property of benzyldibutylamine

Chemical Property:

• Vapor Pressure: 0.00287mmHg at 25°C

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of benzyldibutylamine

There total 33 articles about benzyldibutylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

benzaldehyde (100-52-7) + dibutylamine (111-92-2) → N,N-di-n-butylbenzylamine (4383-27-1)

Guidance literature:

With hydrogen; In toluene; at 140 ℃; for 18h; under 22502.3 Torr;

DOI:10.1039/c6ra21415k

Reference yield: 95.0%

dibutylamine (111-92-2) + benzyl alcohol (100-51-6,185532-71-2) → N,N-di-n-butylbenzylamine (4383-27-1)

Guidance literature:

With Cu₂Al₃Ox-HT; In toluene; at 160 ℃; for 24h; Sealed tube; Inert atmosphere;

DOI:10.1039/c5cc02205c

Reference yield: 88.0%

N,N-dibutylbenzamide (25033-65-2) → N,N-di-n-butylbenzylamine (4383-27-1)

Guidance literature:

With lithium aluminium tetrahydride; sulfuric acid; In tetrahydrofuran; at 20 ℃; for 4h;

DOI:10.1002/anie.201809929

upstream raw materials:

benzyl tri-n-butylammonium bromide

benzyl chloride

dibutylamine

carbon monoxide

Downstream raw materials:

N,N-dibutylacetamide

dibutylamine

1-(4-methoxyphenyl)-1-butanone

N-chloro-N,N-dibutylamine

Refernces

• 1、 Liu, Jianguo,Ma, Longlong,Song, Yanpei,Zhang, Mingyue,Zhuang, Xiuzheng. "Simplified preparation of a graphene-co-shelled Ni/NiO@C nano-catalyst and its application in theN-dimethylation synthesis of amines under mild conditions". supporting information. p. 4604 - 4617. Retrieved 2021/06/30.
• 2、 Onodera, Gen,Kumagae, Hidenobu,Nakamura, Daiki,Hayasaki, Takuto,Fukuda, Tsutomu,Kimura, Masanari. "Direct benzylation of amines with benzylic alcohols catalyzed by palladium/phosphine-borane catalyst system". supporting information. . Retrieved 2020/11/04.