TETRABUTYLAMMONIUM THIOPHENOLATE

Base Information

• Chemical Name: TETRABUTYLAMMONIUM THIOPHENOLATE
• CAS No.: 4670-62-6
• Molecular Formula: C16H36N.C6H5S
• Molecular Weight: 351.64
• Mol file: 4670-62-6.mol

Synonyms:Tetrabutylammonium thiophenolate;n-Tetrabutylammonium thiophenolate;Thiophenol tetrabutylammonium salt;tetrabutylammonium phenylthiolate;tetrabutylamonium benzenethiolate;1-Butanaminium,N,N,N-tributyl-,benzenethiolate;tetra-n-butylammonium thiophenolate;tetra-N-butylammonium benzenethiolate;

Chemical Property of TETRABUTYLAMMONIUM THIOPHENOLATE

Chemical Property:

• Melting Point: 77-85oC
• PSA: 0.00000
• LogP: 6.59600
• Storage Temp.: 2-8°C

Purity/Quality:

95% ^*data from raw suppliers

TETRABUTYLAMMONIUM THIOPHENOLATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of TETRABUTYLAMMONIUM THIOPHENOLATE

There total 3 articles about TETRABUTYLAMMONIUM THIOPHENOLATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

tetrabutyl-ammonium chloride (1112-67-0) + sodium thiophenolate (930-69-8) → tetra-N-butylammonium benzenethiolate (4670-62-6)

Guidance literature:

In tetrahydrofuran; for 4h; Inert atmosphere;

DOI:10.1002/anie.201000695

Reference yield: 97.0%

tetra(n-butyl)ammonium hydroxide (2052-49-5) + thiophenol (108-98-5) → tetra-N-butylammonium benzenethiolate (4670-62-6)

Guidance literature:

In benzene; at 6 - 10 ℃; for 1h;

DOI:10.1007/BF00960427

Reference yield:

thiophenol (108-98-5) + di-tert-butyl phosphoric acid tetra-n-butylammonium salt (68695-48-7) → 2C8H18O4P(1-)*H(1+)*C16H36N(1+) + tetra-N-butylammonium benzenethiolate (4670-62-6)

Guidance literature:

In dichloromethane-d2;

DOI:10.1021/jacs.0c08673

upstream raw materials:

tetra(n-butyl)ammonium hydroxide

thiophenol

tetrabutyl-ammonium chloride

sodium thiophenolate

Downstream raw materials:

Benzyl phenyl sulfide

(C₄H₉)4N⁽¹⁺⁾*[C₆H₅CH₂C(Si(CH₃)3)(Ga(CH₂C(CH₃)3)2)2SC₆H₅]^(1-)=[(C₄H₉)4N][C₆H₅CH₂C(Si(CH₃)3)(Ga(CH₂C(CH₃)3)2)2SC₆H₅]

para-iodoanisole

4-methoxy-7-iodo[2.2]paracyclophane

Refernces

• 1、 Berg, Nele,Bergwinkl, Sebastian,Nuernberger, Patrick,Horinek, Dominik,Gschwind, Ruth M.. "Extended Hydrogen Bond Networks for Effective Proton-Coupled Electron Transfer (PCET) Reactions: The Unexpected Role of Thiophenol and Its Acidic Channel in Photocatalytic Hydroamidations". supporting information. p. 724 - 735. Retrieved 2021/02/01.
• 2、 Rybakova, I. A.,Shekhtman, R. I.,Prilezhaeva, E. N.. "SYNTHESIS OF TETRAALKYLAMMONIUM THIOLATES". . p. 1903 - 1905. Retrieved 2007/10/02.