Magnesium, chloro(2-methylpropyl)-

Base Information

• Chemical Name: Magnesium, chloro(2-methylpropyl)-
• CAS No.: 5674-02-2
• Molecular Formula: C4H9ClMg
• Molecular Weight: 116.873
• Hs Code.: 29319090
• DSSTox Substance ID: DTXSID60884181
• Mol file: 5674-02-2.mol

Synonyms:5674-02-2;ISOBUTYLMAGNESIUM CHLORIDE;Magnesium, chloro(2-methylpropyl)-;ISO-BUTYLMAGNESIUM CHLORIDE;magnesium;2-methanidylpropane;chloride;2-Methylpropylmagnesium chloride;674-02-2;iBuMgCl;i-BuMgCl;i-butylmagnesium chloride;isobutyl magnesium chloride;SCHEMBL11018;Chloro-(2-methylpropyl)magnesium;DTXSID60884181;YUPZOKFCNKSJTR-UHFFFAOYSA-M;MFCD00000471;AKOS015915840;Isobutylmagnesium chloride, 2M in THF;J-802229

Chemical Property of Magnesium, chloro(2-methylpropyl)-

Chemical Property:

• Boiling Point: 65-67 °C
• Flash Point: −40 °F
• PSA: 0.00000
• Density: 0.967 g/mL at 25 °C
• LogP: 2.29950
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 116.0243197
• Heavy Atom Count: 6
• Complexity: 15

Purity/Quality:

99.9% ^*data from raw suppliers

IsobutylmagnesiumChloride(2MinDiethylEther) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F+;C;Xn;F
• Hazard Codes: F+,C,Xn,F
• Statements: 12-14/15-19-22-34-66-36/37/38-14-11-67-15-40-37
• Safety Statements: 7-16-26-29-36/37/39-43-45-23

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(C)[CH2-].[Mg+2].[Cl-]

Technology Process of Magnesium, chloro(2-methylpropyl)-

There total 7 articles about Magnesium, chloro(2-methylpropyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Isobutane (75-28-5,40921-86-6) + isobutyryl chloride (513-36-0) → 2-methylpropylmagnesium chloride (5674-02-2)

Guidance literature:

With H₂; In n-heptane;

Reference yield:

isobutyryl chloride (513-36-0) → 2-methylpropylmagnesium chloride (5674-02-2)

Guidance literature:

With magnesium anthracene * 3 THF; Product distribution; multistep reaction; other procedures for the preparation of Mg^*; other solvents; other halides;

Reference yield:

isobutyryl chloride (513-36-0) → 2-methylpropylmagnesium chloride (5674-02-2)

Guidance literature:

With carbon disulfide; diethyl ether;

upstream raw materials:

9,10-dihydro-9,10-anthracendiyl-tris(THF)magnesium

isobutyryl chloride

Isobutane

Downstream raw materials:

diisobutyl ketone

2-methyl-4-heptanone

isobutyl n-butyrate

3-Methyl-1-phenyl-1-butanol

Refernces

• 1、 Bartmann, Ekkehard,Bogdanovic, Borislav,Janke, Nikolaus,Liao, Shijan,Schlichte, Klaus,et al.. "Active Magnesium from Catalytically Prepared Magnesium Hydride or from Magnesium Anthracene and its Uses in the Synthesis". . p. 1517 - 1528. Retrieved 2007/10/02.