cis-Dichlorobis(2,2'-bipyridine)ruthenium(II) dihydrate

Base Information

• Chemical Name: cis-Dichlorobis(2,2'-bipyridine)ruthenium(II) dihydrate
• CAS No.: 15746-57-3
• Molecular Formula: C20H16 Cl2 N4 Ru
• Molecular Weight: 364.193
• Hs Code.: 29310099
• European Community (EC) Number: 805-738-4,823-614-8
• Mol file: 15746-57-3.mol

Synonyms:15746-57-3;cis-Dichlorobis(2,2'-bipyridine)ruthenium(II) dihydrate;152227-36-6;dichlororuthenium;2-pyridin-2-ylpyridine;dihydrate;609844-11-3;cis-Dichlorobis(2,2'-bipyridine)ruthenium (II) dihydrate;Dichlorobis(2,2'-bipyridine)ruthenium(II)dihydrate;Dichlorobis(2,2'-bipyridine)ruthenium(II) dihydrate;cis-bis-(2,2'-bipyridine)dichlororuthenium(ii) dihydrate;CIS-DICHLOROBIS(2,2/'-BIPYRIDINE)RUTHENIUM (II) DIHYDRATE, 99;MFCD00015504;AKOS024258163;D84819;F20805;10.14272/NHKTUSUPCAKVHT-UHFFFAOYSA-L.1;doi:10.14272/NHKTUSUPCAKVHT-UHFFFAOYSA-L.1;cis-dichlorobis(2,2'-bipyridine)ruthenium(ii)dihydrate;BIS(2,2'-BIPYRIDINE) DICHLORORUTHENIUM DIHYDRATE;cis-Bis(2,2'-bipyridine)dichlororuthenium(II) dihydrate;cis-Dichlorobis(2,2'-bipyridine) ruthenium(II) dihydrate;cis-Dichlorobis-(2,2'-bipyridine)ruthenium-(ii)2-hydrate;Ruthenium, bis(2,2'-bipyridine-kappaN1,kappaN1')dichloro-

Chemical Property of cis-Dichlorobis(2,2'-bipyridine)ruthenium(II) dihydrate

Chemical Property:

• Melting Point: 198-200℃
• Boiling Point: 254.8°Cat760mmHg
• Flash Point: 126.5°C
• PSA: 12.96000
• Density: g/cm³
• LogP: 4.37860
• Water Solubility.: Soluble in water.
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 2
• Exact Mass: 520.000672
• Heavy Atom Count: 29
• Complexity: 123

Purity/Quality:

99% ^*data from raw suppliers

cis-Bis(2,2''-bipyridine)dichlororutheniumDihydrate ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=NC(=C1)C2=CC=CC=N2.C1=CC=NC(=C1)C2=CC=CC=N2.O.O.Cl[Ru]Cl
• Uses: cis-Bis(2,2''-bipyridine)dichlororuthenium Dihydrate is a reactant used in the preparation of phenanthroline-fused pyrazinazenes as photosensitizers.

Technology Process of cis-Dichlorobis(2,2'-bipyridine)ruthenium(II) dihydrate

There total 47 articles about cis-Dichlorobis(2,2'-bipyridine)ruthenium(II) dihydrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

[2,2]bipyridinyl (366-18-7) + dichloro(1,5-cyclooctadiene)ruthenium(II) → cis-dichlorobis(2,2′-bipyridine)ruthenium(II) (345911-20-8,19542-80-4,158060-65-2,34795-02-3,15746-57-3)

Guidance literature:

In N,N-dimethyl-formamide; other Radiation; a suspn. of Ru-complex and bipyridine-compound in DMF was reacted for 45min under microwave irradiation (microwave set-up; 30 s, 600 W; 45 min, 200 W; 10 min, ventilation); the solvent was immediately removed on the rotary evaporator, the solid was washed with diethyl ether and dried on air;

DOI:10.1016/j.ica.2004.07.007

Reference yield: 90.0%

Ru((C5H4N)2)2Cl2(1+)*Cl(1-)*2H2O = {Ru((C5H4N)2)2Cl2}Cl*2H2O → cis-dichlorobis(2,2′-bipyridine)ruthenium(II) (345911-20-8,19542-80-4,158060-65-2,34795-02-3,15746-57-3)

Guidance literature:

With SnCl₂*2HCl; In hydrogenchloride; SnCl2*2HCl added to a soln. of Ru-compd. in HCl; concd. by warming, washed with H2O, air dried;

DOI:10.1016/S0020-1693(00)85316-5

Reference yield: 78.0%

4,4'-bipyridine (553-26-4) + ruthenium(III) chloride trihydrate + lithium chloride → cis-dichlorobis(2,2′-bipyridine)ruthenium(II) (345911-20-8,19542-80-4,158060-65-2,34795-02-3,15746-57-3)

Guidance literature:

In N,N-dimethyl-formamide; for 8h; Reflux; Darkness;

DOI:10.1016/j.jinorgbio.2020.111132

upstream raw materials:

[2,2]bipyridinyl

ruthenium trichloride hydrate

ruthenium(III)chloride

ruthenium(III) chloride hydrate

Downstream raw materials:

{RuCl(py)(bpy)2}⁽¹⁺⁾

chloride

[Ru(2,2'-bipyridine)2(2-(4-formylphenyl)-1H-imidazo-[4,5-f][1,10]phenanthroline)]⁽²⁺⁾

Ru(C₁₀H₈N₂)2(C₆H₄OCHNC₆H₅)⁽¹⁺⁾*ClO₄^(1-)=[Ru(C₁₀H₈N₂)2(C₆H₄OCHNC₆H₅)]ClO₄

Refernces

• 1、 Chen, Jianjiao,He, Xin,Ke, Zhen,Wei, Bo,Yang, Jie,Zou, Dengfeng,Zou, Jianhua,Zou, Zhenyuan. "Two photoactive Ru (II) compounds based on tetrazole ligands for photodynamic therapy". . . Retrieved 2020.
• 2、 Tran, Ngoc-Han,Nguyen, Daniel,Dwaraknath, Sudharsan,Mahadevan, Sruthi,Chavez, Garrett,Nguyen, Angelina,Dao, Thanh,Mullen, Sarah,Nguyen, Thien-Anh,Cheruzel, Lionel E.. "An efficient light-driven P450 BM3 biocatalyst". . p. 14484 - 14487. Retrieved 2013.
• 3、 Zabarska, Natalia,Vos, Johannes G.,Rau, Sven. "A new method for the utilization of compounds of the type [Ru(bpy)2(CO)Cl]+ as a starting material for the synthesis of [Ru(N6)]2+ type compounds". . p. 173 - 175. Retrieved 2015.
• 4、 Aranyos, Viviane,Hagfeldt, Anders,Grennberg, Helena,Figgemeier, Egbert. "Electropolymerisable bipyridine ruthenium(II) complexes: Synthesis, spectroscopic and electrochemical characterisation of 4-((2-thienyl) ethenyl)- and 4,4′-di((2-thienyl) ethenyl)-2,2′ -bipyridine ruthenium complexes". . p. 589 - 598. Retrieved 2004.
• 5、 Aranyos, Viviane,Hjelm, Johan,Hagfeldt, Anders,Grennberg, Helena. "Tuning the properties of ruthenium bipyridine dyes for solar cells by substitution on the ligands - Characterisation of bis[4,4′-di(2-(3- methoxyphenyl)ethenyl)-2,2′ -bipyridine] [4,4′-dicarboxy-2,2′- bipyridine]ruthenium(II) dihexafluorophosphate". . p. 1280 - 1283. Retrieved 2003.
• 6、 Vázquez, Marta,Martínez, Manuel. "Kinetico-mechanistic Studies on the Substitution Reactivity on the {RuII(bpy)2} Core with Nucleosides and Nucleotides at Physiological pH". . p. 6731 - 6738. Retrieved 2016.
• 7、 Togano, Tadashi,Nagao, Noriharu,Tsuchida, Mitsuko,Kumakura, Hiromi,Hisamatsu, Kumiko,et al.. "". . p. 221 - 226. Retrieved 1992.
• 8、 Ng, Sze-Wing,Chung, Lai-Hon,Yeung, Chi-Fung,Lo, Hoi-Shing,Shek, Hau-Lam,Kang, Tian-Shu,Leung, Chung-Hang,Ma, Dik-Lung,Wong, Chun-Yuen. "Metalated Chromene and Chromone Complexes: pH Switchable Metal–Carbon Bonding Interaction, Photo-triggerable Chromone Delivery Application, and Antioxidative Activity". . p. 1779 - 1783. Retrieved 2018.
• 9、 Finck, Sidonie,Issenhuth, Jean-Thomas,Despax, Stéphane,Sirlin, Claude,Pfeffer, Michel,Poidevin, Corentin,Gourlaouen, Christophe,Boeglin, Alex,Daniel, Chantal. "Structural and optical properties of new cyclometalated Ru(II) derived compounds". . p. 248 - 259. Retrieved 2014.
• 10、 Veinot,Farah,Galloro,Zobi,Bell,Pietro. "Surface functionalization of cadmium sulfide quantum confined nanoclusters 6: Evidence of facile electronic communication between remote surface sites". . p. 331 - 341. Retrieved 2000.