Palmitic acid trimethylsilyl ester

Base Information

• Chemical Name: Palmitic acid trimethylsilyl ester
• CAS No.: 55520-89-3
• Molecular Formula: C19H40O2Si
• Molecular Weight: 328.60500
• Mol file: 55520-89-3.mol

Synonyms:Palmitic acid,trimethylsilyl ester;Hexadecanoic acid,trimethylsilyl ester;trimethylsilyl palmitate;

Chemical Property of Palmitic acid trimethylsilyl ester

Chemical Property:

• Boiling Point: 364.3±11.0 °C(Predicted)
• PSA: 26.30000
• Density: 0.861±0.06 g/cm3(Predicted)
• LogP: 6.84580

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Palmitic acid trimethylsilyl ester

There total 5 articles about Palmitic acid trimethylsilyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trimethylsilyl iodide (16029-98-4) + hexadecanoic acid ethyl ester (628-97-7) → hexadecanoic acid trimethylsilyl ester (55520-89-3)

Guidance literature:

In tetrachloromethane;

DOI:10.1021/ja00445a062

Reference yield:

1-hexadecylcarboxylic acid (57-10-3) + 1,1,1,3,3,3-hexamethyl-disilazane (999-97-3) → hexadecanoic acid trimethylsilyl ester (55520-89-3)

Guidance literature:

With chloro-trimethyl-silane; at 70 ℃; for 4h;

DOI:10.1021/jf030751v

Reference yield:

{(E)-3-(chloromethylene)-2,3-dihydrobenzo[b]oxepin-7-yl}methyl palmitate (1032646-48-2) + N-methyl-N-trimethylsilyl-2,2,2-trifluoroacetamide (24589-78-4) → {(E)-3-(chloromethylene)-2,3-dihydrobenzo[b]oxepin-7-yl}methyl trimethysilyl ether (1032646-46-0) + hexadecanoic acid trimethylsilyl ester (55520-89-3)

Guidance literature:

{(E)-3-(chloromethylene)-2,3-dihydrobenzo[b]oxepin-7-yl}methyl palmitate; With methanol; potassium hydroxide; at 60 ℃; for 1h; Heating;

N-methyl-N-trimethylsilyl-2,2,2-trifluoroacetamide;

DOI:10.1002/ejoc.200700812

upstream raw materials:

trimethylsilyl iodide

hexadecanoic acid ethyl ester

1-hexadecylcarboxylic acid

1,1,1,3,3,3-hexamethyl-disilazane

Refernces

• 1、 Peters, Silke,Jaeger, Robert J. R.,Spiteller, Peter. "Benzoxepine esters as precursors of the wound-activated chemical defence of Mycena galopus". body text. p. 1187 - 1194. Retrieved 2009/04/07.