hexamethylborazine

Base Information

• Chemical Name: hexamethylborazine
• CAS No.: 877-07-6
• Molecular Formula: C6H18B3N3
• Molecular Weight: 164.662
• Mol file: 877-07-6.mol

Synonyms:

Chemical Property of hexamethylborazine

Chemical Property:

• Vapor Pressure: 3.22mmHg at 25°C
• Boiling Point: 154.1°C at 760 mmHg
• Flash Point: 47°C
• Density: 0.84g/cm³

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of hexamethylborazine

There total 8 articles about hexamethylborazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

carbon dioxide (124-38-9,18923-20-1) + C7H18B3F3N3(1-)*K(1+) → potassium trifluoroacetate (2923-16-2) + hexamethylborazine (877-07-6)

Guidance literature:

In dimethyl sulfoxide; at 25 ℃; for 12h; under 3040.2 Torr;

DOI:10.1021/jacs.7b05408

Reference yield: 71.0%

C2H10BN (88916-89-6) → hydrogen (1333-74-0) + hexamethylborazine (877-07-6)

Guidance literature:

With cobalt(II) chloride; at 80 ℃;

DOI:10.1071/CH13198

Reference yield: 46.0%

dimethyl{(trimethylsilyl)(trimethylsiloxy)amino}borane (76875-58-6) + tributyl borane (122-56-5) → (butylmethylboryl)(dibutylboryl)methylamine (110569-51-2) + Hexamethyldisiloxane (107-46-0) + hexamethylborazine (877-07-6)

Guidance literature:

mixt. of Me2BN(SiMe3)(OSiMe3) and pentane thermolyzed at 400 K, products added to Bu3B; pentane, disiloxane, hexamethyldisiloxane and excess of Bu3B distd. off in vac.; elem. anal.;

upstream raw materials:

dibromomethylborane

heptamethyldisilazane

dimethyl{(trimethylsilyl)(trimethylsiloxy)amino}borane

tributyl borane

Downstream raw materials:

methane

2,4,6-trichloro-1,3,5-trimethylborazine

C₉H₁₈B₃MnN₃O₃⁽¹⁺⁾*C₃₂H₁₂BF₂₄^(1-)

methylamine

Refernces

• 1、 -. "COMPLEXES FOR NUCLEOPHILIC, RADICAL, AND ELECTROPHILIC POLYFLUOROALKYLATION". Paragraph 00155; 00156. . Retrieved 2018/04/11.
• 2、 Jackson, Logan A.,Allen, Christopher W.. "Organoborazines. Part 2. Synthesis of Alkenyltriborazines". . p. 2423 - 2428. Retrieved 2007/10/02.