1-Propenyl

Base Information

• Chemical Name: 1-Propenyl
• CAS No.: 6067-68-1
• Molecular Formula: C₃H₅
• Molecular Weight: 41.0727
• Mol file: 6067-68-1.mol

Synonyms:

Chemical Property of 1-Propenyl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-Propenyl

There total 8 articles about 1-Propenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

iron monocarbonyl cation (35038-14-3) + 3-chloroprop-1-ene (107-05-1) → FeCl(1+) + C6H10(1+) + FeC3H5Cl(1+) (119909-88-5) + prop-1->3-enylium (1724-46-5,1981-80-2,6067-68-1,15552-77-9,50457-57-3,50457-58-4,65887-19-6,65887-20-9) + iron (1+) (14067-02-8)

Guidance literature:

In gas; reaction with allyl chloride (ca. 1 mTorr) in MS/MS/MS multiquadropole spectrometer (collision gas Ar, 0.7 mTorr; 15-25 eV); according to Beaugrand, C. et al., Int. J. Mass Spectrom. Ion Proc., in press; further products; Kinetics;

DOI:10.1021/ja00191a080

Reference yield:

propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) + trifluoromethylium (18851-76-8) → Vinylidene fluoride (75-38-7) + prop-1->3-enylium (1724-46-5,1981-80-2,6067-68-1,15552-77-9,50457-57-3,50457-58-4,65887-19-6,65887-20-9) + 1-fluoro-ethylium (29526-61-2) + C4H4F(1+) + C4H5F2(1+)

Guidance literature:

Product distribution; Rate constant; Mechanism;

DOI:10.1021/j100010a033

Reference yield:

ethene (74-85-1) + cyanoacetylene cation radical (1070-71-9) → propiolonitrile (1070-71-9) + prop-1->3-enylium (1724-46-5,1981-80-2,6067-68-1,15552-77-9,50457-57-3,50457-58-4,65887-19-6,65887-20-9) + vinyl radical (2669-89-8) + ethylene radical cation (74-85-1)

Guidance literature:

In various solvent(s); at 23.9 ℃; under 0.3 - 0.4 Torr; Product distribution; Rate constant; in a Selected-Ion Flow Tube (SIFT) apparatus;

upstream raw materials:

(Z)-2-Butene

trans-2-propenyl bromide

isobutene

propene

Downstream raw materials:

N-Allyl-pyridinium

C₉H₁₁⁽¹⁺⁾

prop-1-yne

formyl radical

Refernces

• 1、 Forte, Leonard,Lien, Min H.,Hopkinson, Alan C.,Bohme, Diethard K.. "Gas-phase measurements of the kinetics of BF2(+)-induced polymerization of olefinic monomers". . p. 1576 - 1583. Retrieved 2007/10/02.
• 2、 Bowers, Michael T.,Shuying, Liu,Kemper, Petranella,Stradling, Rod,Webb, Hung,et al.. "C3H5+ Isomers: Evidence for the Existence of Long-Lived Allyl and 2-Propenyl Cations in the Gas Phase". . p. 4830 - 4832. Retrieved 2007/10/02.