2-(4-NITROPHENOXY)BENZENECARBOXYLIC ACID

Base Information

• Chemical Name: 2-(4-NITROPHENOXY)BENZENECARBOXYLIC ACID
• CAS No.: 6082-87-7
• Molecular Formula: C13H9NO5
• Molecular Weight: 259.218
• Hs Code.: 2918990090
• Mol file: 6082-87-7.mol

Synonyms:2-(3,4-DICHLOROPHENYL)PENT-4-ENOIC ACID N-METHYLAMIDE;nitrophenoxybenzenecarboxylicacid;2-(4-Nitro-phenoxy)-benzoesaeure;2-(4-nitro-phenoxy)-benzoic acid;o-(o-Nitrophenoxy)benzoic acid;2-(4-nitrophenoxy)benzenecarboxylic acid;2-carboxy-4'-nitrodiphenyl ether;2-<4-Nitro-phenyl>-benzoesaeure;o-carboxyphenyl p-nitrophenyl ether;

Chemical Property of 2-(4-NITROPHENOXY)BENZENECARBOXYLIC ACID

Chemical Property:

• Melting Point: 154-157°C
• PSA: 92.35000
• LogP: 3.60850

Purity/Quality:

98%Min ^*data from raw suppliers

2-(4-Nitrophenoxy)benzoicAcid ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-(4-NITROPHENOXY)BENZENECARBOXYLIC ACID

There total 12 articles about 2-(4-NITROPHENOXY)BENZENECARBOXYLIC ACID which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Salicylsaeure-4-nitrophenylester (17374-48-0) → 4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + o-carboxyphenyl p-nitrophenyl ether (6082-87-7) + salicylic acid (69-72-7,25496-36-0,8052-31-1)

Guidance literature:

With borate buffer; water; β‐cyclodextrin; In acetonitrile; at 25 ℃; pH=10.0; Further Variations:; pH-values; Reagents; Kinetics;

DOI:10.1007/BF01431107

Reference yield:

2-(4-nitrophenoxy)benzaldehyde (62256-41-1) → o-carboxyphenyl p-nitrophenyl ether (6082-87-7)

Guidance literature:

With sodium dichromate; sulfuric acid;

DOI:10.1021/ja01316a035

Reference yield:

2-phenoxybenzoic acid (2243-42-7) → o-carboxyphenyl p-nitrophenyl ether (6082-87-7)

Guidance literature:

With nitric acid;

DOI:10.1021/ja01316a035

upstream raw materials:

1-methyl-2-(4-nitrophenoxy)benzene

2-(4-nitrophenoxy)benzaldehyde

Salicylsaeure-4-nitrophenylester

4-nitro-phenol

Downstream raw materials:

methyl2-(4-nitrophenoxy)benzoate

2-(4-nitro-phenoxy)-benzoyl chloride

2-(4-aminophenoxy)-N-(2-methoxyphenyl)benzamide

morpholino(2-(4-nitrophenoxy)phenyl)methanone

Refernces

• 1、 Gonzalez-Gomez, Jose C.,Ramirez, Nieves P.,Lana-Villarreal, Teresa,Bonete, Pedro. "A photoredox-neutral Smiles rearrangement of 2-aryloxybenzoic acids". . p. 9680 - 9684. Retrieved 2017/11/30.
• 2、 Yatsimirsky,Bezsoudnova. "Effects of cyclodextrin on hydrolysis and the Smiles rearrangement of salicylic acid esters". . p. 2517 - 2524. Retrieved 2007/10/03.