fluoro(4-methoxyphenyl)dimethylsilane

Base Information

• Chemical Name: fluoro(4-methoxyphenyl)dimethylsilane
• CAS No.: 62244-55-7
• Molecular Formula: C9H13FOSi
• Molecular Weight: 184.286
• Mol file: 62244-55-7.mol

Synonyms:

Chemical Property of fluoro(4-methoxyphenyl)dimethylsilane

Chemical Property:

• Vapor Pressure: 0.456mmHg at 25°C
• Boiling Point: 200.6°Cat760mmHg
• Flash Point: 75.1°C
• Density: 0.98g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of fluoro(4-methoxyphenyl)dimethylsilane

There total 2 articles about fluoro(4-methoxyphenyl)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chlorodimethyl(4-methoxyphenyl)silane (2372-33-0) → (p-Methoxy-phenyl)-dimethyl-fluorsilan (62244-55-7) + methoxybenzene (100-66-3)

Guidance literature:

With potassium hydrogen bifluoride; for 0.5h; Yield given; Heating;

DOI:10.1016/0022-328X(94)88026-3

Reference yield:

1-bromo-4-methoxy-benzene (104-92-7) → (p-Methoxy-phenyl)-dimethyl-fluorsilan (62244-55-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 1.) Mg / 1.) ether, 2.) ether, RT, 30 min

2: KHF₂ / 0.5 h / Heating

With potassium hydrogen bifluoride; magnesium;

DOI:10.1016/0022-328X(94)88026-3

Reference yield:

bis(trimethylsilyl)dichloromethane (15951-41-4) + (p-Methoxy-phenyl)-dimethyl-fluorsilan (62244-55-7) → 1-[(Chloro-bis-trimethylsilanyl-methyl)-dimethyl-silanyl]-4-methoxy-benzene (125364-51-4)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; diethyl ether; pentane; at -110 - 20 ℃;

DOI:10.1039/c39890000595

upstream raw materials:

chlorodimethyl(4-methoxyphenyl)silane

1-bromo-4-methoxy-benzene

Downstream raw materials:

1,3-bis(4′-methoxyphenyl)-1,1,3,3-tetramethyldisiloxane

1-[(Chloro-bis-trimethylsilanyl-methyl)-dimethyl-silanyl]-4-methoxy-benzene

1-[(Dimethylsilanyl-bis-trimethylsilanyl-methyl)-dimethyl-silanyl]-4-methoxy-benzene

1-{[(Iodo-dimethyl-silanyl)-bis-trimethylsilanyl-methyl]-dimethyl-silanyl}-4-methoxy-benzene

Refernces