Tributylmethylammonium bromide

Base Information

• Chemical Name: Tributylmethylammonium bromide
• CAS No.: 37026-88-3
• Molecular Formula: C13H30BrN
• Molecular Weight: 280.292
• Hs Code.: 2923900090
• European Community (EC) Number: 253-313-1
• DSSTox Substance ID: DTXSID00958198
• Mol file: 37026-88-3.mol

Synonyms:37026-88-3;Tributylmethylammonium bromide;Methyltributylammonium bromide;Methyl tributyl ammonium bromide;1-Butanaminium, N,N-dibutyl-N-methyl-, bromide;tributyl(methyl)azanium;bromide;EINECS 253-313-1;N,N-dibutyl-N-methylbutan-1-aminium bromide;Methyltri-n-Butylammonium Bromide;SCHEMBL238424;tributylmethylammonium bro-mide;Tri-n-butylmethylammonium bromide;DTXSID00958198;MFCD00043201;AKOS024437842;Tributylmethylammonium bromide, >=98.0%;CS-0451726;FT-0660876;E79215

Chemical Property of Tributylmethylammonium bromide

Chemical Property:

• Melting Point: 120-122 °C
• Boiling Point: 259oC at 760mmHg
• Flash Point: 106.2oC
• PSA: 0.00000
• LogP: 0.83730
• Sensitive.: Hygroscopic
• Solubility.: H2O: 0.1 g/mL, clear, colorless
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 9
• Exact Mass: 279.15616
• Heavy Atom Count: 15
• Complexity: 98.6

Purity/Quality:

99% ^*data from raw suppliers

Tributylmethylammonium bromide ≥98.0% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCCC[N+](C)(CCCC)CCCC.[Br-]

Technology Process of Tributylmethylammonium bromide

There total 2 articles about Tributylmethylammonium bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methyl bromide (74-83-9) + tributyl-amine (102-82-9) → N-methyl-tri-n-butyl-ammonium bromide (37026-88-3)

Guidance literature:

With acetone;

DOI:10.1021/ja01527a023

Reference yield:

→ N-methyl-tri-n-butyl-ammonium bromide (37026-88-3)

Guidance literature:

Tributyl-methyl-ammoniumiodid, Br-Ionenaustauscher;

Reference yield: 99.5%

sodium thiophenolate (930-69-8) + N-methyl-tri-n-butyl-ammonium bromide (37026-88-3) → methyl-phenyl-thioether (100-68-5)

Guidance literature:

In butan-1-ol; at 115 ℃; for 5h;

upstream raw materials:

methyl bromide

tributyl-amine

Downstream raw materials:

1-butylene

tributyl-amine

methane

N-methyldibutylamine

Refernces