3-Tetradecanol

Base Information

• Chemical Name: 3-Tetradecanol
• CAS No.: 1653-32-3
• Molecular Formula: C14H30 O
• Molecular Weight: 214.392
• Hs Code.: 2905199090
• Mol file: 1653-32-3.mol

Synonyms:(?à)-3-Tetradecanol

Chemical Property of 3-Tetradecanol

Chemical Property:

• Vapor Pressure: 0.000628mmHg at 25°C
• Melting Point: 31.5°C
• Refractive Index: 1.4340
• Boiling Point: 275.7°Cat760mmHg
• PKA: 15.27±0.20(Predicted)
• Flash Point: 110.4°C
• PSA: 20.23000
• Density: 0.832g/cm³
• LogP: 4.67820

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3-Tetradecanol

There total 9 articles about 3-Tetradecanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.4%

5-undecyl-1,2-oxathiolane 2,2-dioxide (5981-19-1) → 3-tetradecanol (1653-32-3,4476-77-1) + 1-mercapto-3-tetradecanol (75732-56-8)

Guidance literature:

With lithium aluminium tetrahydride; aluminium trichloride; In diethyl ether; for 42h; Heating;

DOI:10.1021/jo00314a022

Reference yield:

tetradecane (629-59-4) → 3-tetradecanol (1653-32-3,4476-77-1) + 1-Tetradecanol (112-72-1) + 6-tetradecanol (6836-39-1) + 5-tetradecanol (21078-83-1) + tetradecan-4-ol (1653-33-4) + tetradecan-2-ol (4706-81-4)

Guidance literature:

With iodosylbenzene; MnTTPPP(OAc); In benzene; at 25 ℃; for 7h; Mechanism; other catalysts and regioselectivity investigated;

DOI:10.1021/ja00283a024

Reference yield:

tetradecane (629-59-4) → 3-tetradecanol (1653-32-3,4476-77-1) + tetradecan-7-ol (3981-79-1) + tetradecan-7-one (6137-34-4) + tetradecan-5-one (31857-89-3) + 6-tetradecanone (6836-42-6)

Guidance literature:

With air; [Te₂W₂₀O₇₀(RuC₆H₆)₂]^8- anchored on 3-aminopropyltriethoxysilane-modified SBA-15; In neat (no solvent); at 150 ℃; for 6h; Temperature; Catalytic behavior; Green chemistry;

DOI:10.1039/c6nj01914e

upstream raw materials:

ethylmagnesium iodide

Dodecanal

tetradecan-3-one

5-undecyl-1,2-oxathiolane 2,2-dioxide

Downstream raw materials:

tetradecan-3-one

Refernces

• 1、 Cook, Bruce R.,Reinert, Thomas J.,Suslick, Kenneth S.. "Shape Selective Alkane Hydroxylation by Metalloporphyrin Catalysts". . p. 7281 - 7286. Retrieved 2007/10/02.
• 2、 Smith, Michael B.,Wolinsky, Joseph. "Lithium aluminum hydride-aluminum hydride reduction of sultones". . p. 101 - 106. Retrieved 2007/10/02.