Methanol, iron(3+) salt

Base Information

• Chemical Name: Methanol, iron(3+) salt
• CAS No.: 7245-25-2
• Molecular Formula: 2CH₃O*Fe
• Molecular Weight: 117.915
• Mol file: 7245-25-2.mol

Synonyms:

Chemical Property of Methanol, iron(3+) salt

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Methanol, iron(3+) salt

There total 6 articles about Methanol, iron(3+) salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

iron(III) chloride + sodium methylate (124-41-4) → iron(III) methoxide (7245-21-8,7245-25-2,92274-53-8)

Guidance literature:

In ethanol; toluene; for 8h; Inert atmosphere;

DOI:10.1039/c4dt03491k

Reference yield:

methanol (67-56-1) + (C2H5)2Fe(2,2'-bipyridyl)2 → Eisen(II)-methylat (7245-21-8,7245-25-2,92274-53-8)

Guidance literature:

In tetrahydrofuran; byproducts: C2H6; under N2, alcohol added to THF soln. of Fe complex at -78°C, react. vessel evacuated, mixt. allowed to react at room temp. for 1 d; concd., diethyl ether added, ppt. filtered, washed with hexane and diethyl ether a few times, dried in vac., elem. anal.;

DOI:10.1246/bcsj.53.673

Reference yield:

sodium methylate (124-41-4) + iron(II) (7439-89-6,15438-31-0) + cyclopenta-1,3-diene (542-92-7,25568-84-7,7313-32-8) → ferrocene (102-54-5,55404-68-7) + Eisen(II)-methylat (7245-21-8,7245-25-2,92274-53-8)

Guidance literature:

In not given; addn. of C5H6 to Fe(2+) halogenide at ambient temp. and presence of high excess of NaOCH3;;

upstream raw materials:

methanol

Fe₂(O^tBu)₆

sodium methylate

iron(II)

Refernces

• 1、 Kusserow,Spandl. "Alcoholysis of [Fe2(OtBu)6] as a simple route to new iron(III)-alkoxo compounds: Synthesis and crystal structures of (2), (3), (4), (5), (6), (7), and (8)". . p. 885 - 892. Retrieved 2008/10/09.