Cyclohexane, 1-methylene-2-(2-propenyl)-

Base Information

• Chemical Name: Cyclohexane, 1-methylene-2-(2-propenyl)-
• CAS No.: 7335-58-2
• Molecular Formula: C10H16
• Molecular Weight: 136.237
• DSSTox Substance ID: DTXSID80450342
• Nikkaji Number: J477.567H
• Mol file: 7335-58-2.mol

Synonyms:7335-58-2;Cyclohexane, 1-methylene-2-(2-propenyl)-;1-Allyl-2-methylenecyclohexane;2-allyl-1-methylenecyclohexane;DTXSID80450342;Cyclohexane, 1-allyl-2-methylene-

Chemical Property of Cyclohexane, 1-methylene-2-(2-propenyl)-

Chemical Property:

• XLogP3: 3.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 136.125200510
• Heavy Atom Count: 10
• Complexity: 133

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CCC1CCCCC1=C

Technology Process of Cyclohexane, 1-methylene-2-(2-propenyl)-

There total 1 articles about Cyclohexane, 1-methylene-2-(2-propenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

2-allylcyclohexan-1-one (94-66-6) + Methyltriphenylphosphonium bromide (1779-49-3) → 1-allyl-2-methylenecyclohexane (7335-58-2)

Guidance literature:

Methyltriphenylphosphonium bromide; With n-butyllithium; In tetrahydrofuran; at 0 ℃; for 0.5h; Inert atmosphere;

2-allylcyclohexan-1-one; In tetrahydrofuran; at -78 - 20 ℃; Inert atmosphere;

DOI:10.1021/acs.orglett.6b03090

Reference yield: 95.0%

phenylsilane (694-53-1) + 1-allyl-2-methylenecyclohexane (7335-58-2) → [(3aS,7aS)-1-(Octahydro-inden-3a-yl)methyl]-phenyl-silane

Guidance literature:

With <(Cp^TMS)2YMe>2; In cyclohexane; for 1h; Ambient temperature;

DOI:10.1021/jo972359k

Reference yield: 91.0%

phenylsilane (694-53-1) + 1-allyl-2-methylenecyclohexane (7335-58-2) → 1-methylene-2-<3-(phenylsilyl)propyl>cyclohexane

Guidance literature:

yttrium(pentamethylcyclopentadienyl)2CH(trimethylsilyl)2; In benzene; for 92h; Ambient temperature;

DOI:10.1021/jo00049a056

upstream raw materials:

2-allylcyclohexan-1-one

Methyltriphenylphosphonium bromide

Downstream raw materials:

6-Allyl-3-trityl-1-oxa-2-aza-spiro[4.5]dec-2-ene

3-triphenylmethyl-5-<((2-methylene)-cyclohex-1-yl)methyl>-2-isoxazoline

1-Methyl-bicyclo<4.3.0>nonan

2-n-propyl-1-methylenecyclohexane

Refernces