Technology Process of Tributyl[(4-methoxyphenyl)methyl]stannane
There total 3 articles about Tributyl[(4-methoxyphenyl)methyl]stannane which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
N'-(4-methoxybenzylidene)-4-methylbenzenesulfonohydrazide;
With
tetrabutyl-ammonium chloride; sodium hydride;
In
toluene; mineral oil;
at 20 ℃;
for 0.166667h;
Inert atmosphere;
tri-n-butyl-tin hydride;
In
toluene; mineral oil;
at 110 ℃;
for 6h;
- Guidance literature:
-
tetrakis(triphenylphosphine) palladium(0);
In
toluene;
byproducts: (C4H9)3SnCl, (p-MeOC6H4CH2)2; at 115°C for 15 h in sealed thick wall Pyrex glass ampoules;
DOI:10.1016/S0022-328X(00)84615-X
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: toluene / 1 h / 80 °C / Inert atmosphere; Schlenk technique; Sealed tube
2.1: sodium hydride; tetrabutyl-ammonium chloride / toluene / 0.17 h / 20 °C / Inert atmosphere; Schlenk technique
2.2: 6 h / 110 °C / Inert atmosphere; Schlenk technique
With
tetrabutyl-ammonium chloride; sodium hydride;
In
toluene;
DOI:10.1021/acs.joc.6b02639
