Bromic acid;silver

Base Information

• Chemical Name: Bromic acid;silver
• CAS No.: 7783-89-3
• Molecular Formula: AgBrO3
• Molecular Weight: 235.77
• Hs Code.: 28432900
• Mol file: 7783-89-3.mol

Synonyms:

Chemical Property of Bromic acid;silver

Chemical Property:

• Appearance/Colour: White powder and lumps
• PSA: 57.20000
• Density: 5.206g/mLat 25°C(lit.)
• LogP: 0.48920
• Water Solubility.: g/100g solution H2O: 0.193 (25°C), 1.325 (90°C) [KRU93]
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 234.81600
• Heavy Atom Count: 5
• Complexity: 49.8

Purity/Quality:

98%min ^*data from raw suppliers

SILVERBROMATE,97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): O,Xi
• Hazard Codes: O,Xi
• Statements: 8-36/37/38
• Safety Statements: 17-26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: OBr(=O)=O.[Ag]
• Uses: Silver bromate is useful oxidant for the transformation of tetrahydropyranyl ethers to carbonyl compounds.1

Technology Process of Bromic acid;silver

There total 17 articles about Bromic acid;silver which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

potassium bromate (7758-01-2) + silver nitrate → silver bromate (7783-89-3)

Guidance literature:

In water; an aq. soln. of AgNO3 is added dropwise to a stirred aq. soln. of KBrO3under reflux over 3 min, refluxed for 5 min; cooled to room temp., the ppt. is filtd., washed eith cooled distilled water, then with acetone, dried;

DOI:10.1080/00397919408011700

Reference yield:

bromate (15541-45-4) → silver bromate (7783-89-3)

Guidance literature:

With silver nitrate; In not given;

Reference yield:

bromic acid (7789-31-3) + silver carbonate → silver bromate (7783-89-3)

Guidance literature:

In water; excess of aq. HBrO3 soln.;

upstream raw materials:

bromic acid

bromine

silver⁽¹⁺⁾ stearate

nitric acid

Downstream raw materials:

bromic acid

bromine chloride

bromine

sulfuric acid

Refernces

• 1、 Janardhanan, Sivasankaran nair,Kalidas, Chatty. "Preferential Solvation of Ag(I) Bromate and Iodate in Dimethyl Sulfoxide-Water Mixtures". . p. 2363 - 2365. Retrieved 1980.
• 2、 Hendrixson, W. S.. "". . p. 637 - 641. Retrieved 1903.
• 3、 Sharma, Raj Pal,Bala, Ritu,Sharma, Rajni,Perez, Julio,Miguel, Daniel. "Second-sphere coordination complexes via hydrogen bonding: Synthesis, characterization of [Co(NH3)6](XO3)3·nH2O (X=Br, I) and single crystal X-ray structure determination of [Co(NH3)6<". . p. 49 - 54. Retrieved 2006.
• 4、 Jach, J.,Harbottle, G.. "". . p. 520 - 525. Retrieved 1958.
• 5、 Firouzabadi,Mohammadpoor-Baltork. "Lewis acid promoted reactions. IV. Oxidation deprotection of trimethylsilyl ethers with silver and sodium bromates; AgBrO3, NaBrO3". . p. 1065 - 1077. Retrieved 2007/10/02.