1,1'-DIETHYLFERROCENE

Base Information

• Chemical Name: 1,1'-DIETHYLFERROCENE
• CAS No.: 1273-97-8
• Molecular Formula: C14H18Fe
• Molecular Weight: 242.144
• Hs Code.: 29310099
• Mol file: 1273-97-8.mol

Synonyms:Iron,bis(ethylcyclopentadienyl)- (6CI,7CI);1,1'-Diethylferrocene;

Chemical Property of 1,1'-DIETHYLFERROCENE

Chemical Property:

• Appearance/Colour: clear dark orange to dark red brown liquid
• Refractive Index: n20/D 1.58(lit.)
• Boiling Point: 284 °C(lit.)
• Flash Point: 110 °C
• PSA: 0.00000
• Density: 1.18 g/cm³
• LogP: 3.60090
• Storage Temp.: Inert atmosphere,Room Temperature
• Water Solubility.: Insoluble

Purity/Quality:

98% ^*data from raw suppliers

Bis(ethylcyclopentadienyl)iron, min. 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T
• Hazard Codes: T
• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of 1,1'-DIETHYLFERROCENE

There total 19 articles about 1,1'-DIETHYLFERROCENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1,1'-diacetylferrocene (1273-94-5) + dimethyl sulfide borane (13292-87-0) → 1,1'-diethylferrocene (1273-97-8)

Guidance literature:

In tetrahydrofuran; 6 equiv of borane, THF, reflux, 15 min;

DOI:10.1016/S0022-328X(01)00936-6

Reference yield: 94.0%

1,1'-diacetylferrocene (1273-94-5) + sodium cyanoborohydride (25895-60-7) → 1,1'-diethylferrocene (1273-97-8)

Guidance literature:

With boron trifluoride diethyl etherate; In tetrahydrofuran; ammonium hydroxide; dichloromethane; addn. of BF3*OEt2 to a stirred soln. of the 1,1'-diacylferrocene in THF at 25°C, addn. of NaBH3CN over 10 min, stirring (1 h), diln. withCH2Cl2, addn. of aq. NH3 to pH 10; layer sepn., drying (Na2SO4), concn., flash chromy. (SiO2; hexanes/Et2O);

Reference yield: 92.0%

1,1'-diacetylferrocene (1273-94-5) → 1,1'-diethylferrocene (1273-97-8)

Guidance literature:

With sodium tetrahydroborate; In dichloromethane; trifluoroacetic acid; B-compd. addn. to stirred Fe-complex soln., mixt. stirring at 25°C for 1 h, diln. (CH2Cl2), quenching in aq. NaOH, org. layer sepn., drying over Na2SO4, solvent removal; residue flash chromy. (SiO2, Et2O/hexanes 1:9);

DOI:10.1039/p19960001381

upstream raw materials:

iron

spiro[2.4]heptane

1,1'-diacetylferrocene

water

Downstream raw materials:

1,1'-diethylferrocenium bis(trifluoromethanesulfonyl)amide

bis(η⁵-ethylcyclopentadienyl)ruthenium

Refernces

• 1、 Domracheva,Karyakin,Sheiman,Kamelova,Larina,Suvorova,Domrachev. "Thermodynamics and molecular dynamics of some ferrocene derivatives". . p. 1647 - 1655. Retrieved 1999.
• 2、 Bhattacharyya, Sukanta. "Simple reduction of ferrocenyl aldehydes and ketones by sodium boranuide in trifluoroacetic acid: New, efficient, general preparation of alkylferrocenes". . p. 1381 - 1383. Retrieved 1996.
• 3、 Chen, Hui,Niu, Zhihui,Zhao, Yu. "Redox-active binary eutectics: Preparation and their electrochemical properties". . . Retrieved 2021/04/19.
• 4、 -. "Ferrocenyl-based redox-reversible surfactant and preparation method of thereof". Paragraph 0020; 0022. . Retrieved 2018/01/19.