Ethylidene, 2,2,2-trifluoro-1-phenyl-

Base Information

• Chemical Name: Ethylidene, 2,2,2-trifluoro-1-phenyl-
• CAS No.: 81123-05-9
• Molecular Formula: C8H5F3
• Molecular Weight: 158.123
• Mol file: 81123-05-9.mol

Synonyms:

Chemical Property of Ethylidene, 2,2,2-trifluoro-1-phenyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ethylidene, 2,2,2-trifluoro-1-phenyl-

There total 3 articles about Ethylidene, 2,2,2-trifluoro-1-phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-phenyl-3-(trifluoromethyl)-3H-diazirine (73899-14-6) → 1-phenyl-2,2,2-trifluoroethylidene (81123-05-9)

Guidance literature:

In cyclohexane; for 2h; Kinetics; Heating; thermal decomposition, 82.4-97.7 deg C;

DOI:10.1039/P29860000211

Reference yield:

3-phenyl-3-(trifluoromethyl)-3H-diazirine (73899-14-6) → phenyltrifluorodiazoethane (13652-07-8) + 1-phenyl-2,2,2-trifluoroethylidene (81123-05-9)

Guidance literature:

In solid matrix; at -261.2 ℃; Irradiation;

DOI:10.1007/BF00959409

Reference yield:

phenyltrifluorodiazoethane (13652-07-8) → 1-phenyl-2,2,2-trifluoroethylidene (81123-05-9)

Guidance literature:

In cyclohexane; Kinetics; Heating; thermal decomposition, 73.0-97.5 deg C;

DOI:10.1039/P29860000211

upstream raw materials:

3-phenyl-3-(trifluoromethyl)-3H-diazirine

phenyltrifluorodiazoethane

Refernces

• 1、 Bi, Liting,DiLabio, Gino A.,Musolino, Stefania F.,Pei, Zhipeng,Wulff, Jeremy E.. "Structure-function relationships in aryl diazirines reveal optimal design features to maximize C-H insertion". . p. 12138 - 12148. Retrieved 2021/09/28.
• 2、 Noller, Bastian,Poisson, Lionel,Maksimenka, Raman,Fischer, Ingo,Mestdagh, Jean-Michel. "Femtosecond dynamics of isolated phenylcarbenes". supporting information; experimental part. p. 14908 - 14909. Retrieved 2009/03/12.