3-Oxetanemethanol, 3-methyl-, nitrate

Base Information

• Chemical Name: 3-Oxetanemethanol, 3-methyl-, nitrate
• CAS No.: 84051-81-0
• Molecular Formula: C5H9NO4
• Molecular Weight: 147.131
• Mol file: 84051-81-0.mol

Synonyms:3-nitratomethyl-3-methyl oxetane;3-Oxetanemethanol,3-methyl-,nitrate;3-methyl-3-nitratomethyloxetane;3-Methyl-3-oxetanemethyl nitrate;

Chemical Property of 3-Oxetanemethanol, 3-methyl-, nitrate

Chemical Property:

• PSA: 95.51000
• LogP: 0.19070

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3-Oxetanemethanol, 3-methyl-, nitrate

There total 7 articles about 3-Oxetanemethanol, 3-methyl-, nitrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

3-hydroxymethyl-3-methyloxethane (3143-02-0) → 3-methyl-3-(nitroxymethyl)oxetane (84051-81-0)

Guidance literature:

With carbon dioxide; dinitrogen pentoxide; at 0 ℃; for 0.5h; under 45004.5 - 60006 Torr; Autoclave;

DOI:10.1016/j.mencom.2012.03.004

Reference yield: 83.0%

methanesulfonic acid 3-methyloxetan-3-ylmethyl ester (3864-43-5) → 3-methyl-3-(nitroxymethyl)oxetane (84051-81-0)

Guidance literature:

With sodium nitrate; tetrabutylammonium nitrate; In acetonitrile; at 80 ℃; for 24h;

DOI:10.1016/j.jfluchem.2021.109861

Reference yield: 71.0%

(3-methyloxetan-3-yl)methyl 4-methylbenzenesulfonate (99314-44-0) → 3-methyl-3-(nitroxymethyl)oxetane (84051-81-0)

Guidance literature:

With sodium nitrate; tetrabutylammonium nitrate; In water; benzene; at 120 ℃; for 96h;

DOI:10.1055/s-1994-25503

upstream raw materials:

3-hydroxymethyl-3-methyloxethane

trimethylolethane trinitrate

(3-methyloxetan-3-yl)methyl 4-methylbenzenesulfonate

1,1,1-Trimethylolethane dinitrate

Downstream raw materials:

3-hydroxymethyl-3-methyloxethane

ethyl nitrate

Refernces

• 1、 Kuchurov, Ilya V.,Fomenkov, Igor V.,Zlotin, Sergei G.,Tartakovsky, Vladimir A.. "Synthesis of nitric acid esters from alcohols in a dinitrogen pentoxide/carbon dioxide liquid system". experimental part. p. 67 - 69. Retrieved 2012/07/02.
• 2、 Golding,Millar,Paul,Richards. "Preparation of di- and polynitrates by ring-opening nitration of oxetanes by dinitrogen pentoxide (N2O5)". . p. 7051 - 7062. Retrieved 2007/10/02.