2-O-(2,3,4-tri-O-acetyl-6-deoxy-alpha-L-mannopyranosyl)-D-glucose tetraacetate

Base Information

• Chemical Name: 2-O-(2,3,4-tri-O-acetyl-6-deoxy-alpha-L-mannopyranosyl)-D-glucose tetraacetate
• CAS No.: 96646-72-9
• Molecular Formula: C₂₆H₃₆O₁₇
• Molecular Weight: 620.562
• Mol file: 96646-72-9.mol

Synonyms:2-O-(2,3,4-tri-O-acetyl-6-deoxy-alpha-L-mannopyranosyl)-D-glucose tetraacetate

Chemical Property of 2-O-(2,3,4-tri-O-acetyl-6-deoxy-alpha-L-mannopyranosyl)-D-glucose tetraacetate

Chemical Property:

• Boiling Point: 593.6°Cat760mmHg
• Flash Point: 245.8°C
• PSA: 211.79000
• Density: 1.32g/cm³
• LogP: -0.37400

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-O-(2,3,4-tri-O-acetyl-6-deoxy-alpha-L-mannopyranosyl)-D-glucose tetraacetate

There total 3 articles about 2-O-(2,3,4-tri-O-acetyl-6-deoxy-alpha-L-mannopyranosyl)-D-glucose tetraacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ Acetic acid (2S,3S,4S,5S,6S)-2,5-diacetoxy-6-acetoxymethyl-3-((2R,3S,4R,5R,6R)-3,4,5-triacetoxy-6-methyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-4-yl ester (17073-41-5,19949-47-4,35904-56-4,35904-57-5,52921-44-5,52921-45-6,58927-27-8,58927-28-9,58927-29-0,58927-30-3,87236-43-9,87236-44-0,96646-72-9,120787-35-1)

Guidance literature:

entspr. α-D-Galactopyranose Derivat IIa, 1.) Ueberfuehrung in Bromid IIc, 2.) Hg(OAc)2, Eg.;

DOI:10.1007/BF01935705

Reference yield:

→ Acetic acid (2R,3S,4S,5S,6S)-2,5-diacetoxy-6-acetoxymethyl-3-((2R,3S,4R,5R,6R)-3,4,5-triacetoxy-6-methyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-4-yl ester (17073-41-5,19949-47-4,35904-56-4,35904-57-5,52921-44-5,52921-45-6,58927-27-8,58927-28-9,58927-29-0,58927-30-3,87236-43-9,87236-44-0,96646-72-9,120787-35-1)

Guidance literature:

2.3.4-Tri-O-acetyl-α-L-rhamnopyranosyl-bromid III, 1.3.4.6-Tetra-O-acetyl-α-D-galactopyranose IV;

DOI:10.1007/BF01935705

Reference yield:

acetic anhydride (108-24-7) + 2-O-α-L-rhamnopyranosyl-D-galactopyranose (2781-65-9,16741-18-7,19949-48-5,36476-16-1,80876-56-8,137171-16-5,137171-17-6,137171-18-7,137171-19-8,146076-26-8) → Acetic acid (3R,4S,5S,6R)-2,5-diacetoxy-6-acetoxymethyl-3-((2S,3R,4R,5S,6S)-3,4,5-triacetoxy-6-methyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-4-yl ester (17073-41-5,19949-47-4,35904-56-4,35904-57-5,52921-44-5,52921-45-6,58927-27-8,58927-28-9,58927-29-0,58927-30-3,87236-43-9,87236-44-0,96646-72-9,120787-35-1)

Guidance literature:

With pyridine;

DOI:10.1016/S0008-6215(00)80970-2

upstream raw materials:

acetic anhydride

2-O-α-L-rhamnopyranosyl-D-galactopyranose

Refernces