3-(9H-Carbazol-9-yl)phenylboronic acid

Base Information

• Chemical Name: 3-(9H-Carbazol-9-yl)phenylboronic acid
• CAS No.: 864377-33-3
• Molecular Formula: C18H14BNO2
• Molecular Weight: 287.126
• Hs Code.: 2933990090
• Mol file: 864377-33-3.mol

Synonyms:3-(9H-Carbazol-9-yl)phenylboronic acid;

Chemical Property of 3-(9H-Carbazol-9-yl)phenylboronic acid

Chemical Property:

• Boiling Point: 472.6±51.0 °C at 760 mmHg
• PKA: 8.30±0.10(Predicted)
• Flash Point: 239.6±30.4 °C
• PSA: 45.39000
• Density: 1.2±0.1 g/cm³
• LogP: 2.46350
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature

Purity/Quality:

99.5% ^*data from raw suppliers

3-(9H-Carbazol-9-yl)phenylboronicacid ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: suzuki reaction

Technology Process of 3-(9H-Carbazol-9-yl)phenylboronic acid

There total 9 articles about 3-(9H-Carbazol-9-yl)phenylboronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

9-(3-bromophenyl)carbazole (185112-61-2) + Trimethyl borate (121-43-7,63156-11-6) → 3-(9H-carbazol-9-yl)phenylboronic acid (864377-33-3)

Guidance literature:

9-(3-bromophenyl)carbazole; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 1h;

Trimethyl borate; In tetrahydrofuran; at 20 ℃;

Reference yield: 59.5%

C24H26BNO2 → 3-(9H-carbazol-9-yl)phenylboronic acid (864377-33-3)

Guidance literature:

With hydrogenchloride; water; In tetrahydrofuran; n-heptane; dichloromethane;

Reference yield:

9-(3-bromophenyl)carbazole (185112-61-2) → 3-(9H-carbazol-9-yl)phenylboronic acid (864377-33-3)

Guidance literature:

9-(3-bromophenyl)carbazole; With n-butyllithium; In tetrahydrofuran; hexane; at -65 - -60 ℃; for 0.783333h; Cooling in ethanol bath;

With Triisopropyl borate; In tetrahydrofuran; hexane; at 20 ℃; for 2.2h;

With hydrogenchloride; water; In tetrahydrofuran; hexane; for 0.5h;

upstream raw materials:

9-(3-bromophenyl)carbazole

9H-carbazole

Trimethyl borate

1,3-dibromobenzene

Downstream raw materials:

2,6-bis(3-(9H-carbazol-9-yl)phenyl)-N,N-diphenylpyridin-4-amine

9-(3’-bromo-[1,1’-biphenyl]-3-yl)-9H-carbazole

Refernces

• 1、 -. "ORGANIC COMPOUNDS, ORGANIC LIGHT EMITTING DIODE AND ORGNIC LIGHT EMITTING DEVICE HAVING THE COMPOUNDS". . . Retrieved 2019/06/13.
• 2、 -. "Organic electroluminescent material and application thereof". Paragraph 0034-0036. . Retrieved 2018/09/28.