Technology Process of Benzene, [(2-methylene-6-heptenyl)thio]-
There total 4 articles about Benzene, [(2-methylene-6-heptenyl)thio]- which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: DIBAL-H / tetrahydrofuran; toluene / 20 °C
2.1: hexamethylphosphorous triamide; CCl4 / tetrahydrofuran / 0.33 h / -78 °C
2.2: triethylamine / tetrahydrofuran / 5 h
With
tetrachloromethane; diisobutylaluminium hydride; Hexamethylphosphorous triamide;
In
tetrahydrofuran; toluene;
DOI:10.1021/jo052035t
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: K2CO3 / H2O / 3 h / 80 °C
2.1: DIBAL-H / tetrahydrofuran; toluene / 20 °C
3.1: hexamethylphosphorous triamide; CCl4 / tetrahydrofuran / 0.33 h / -78 °C
3.2: triethylamine / tetrahydrofuran / 5 h
With
tetrachloromethane; diisobutylaluminium hydride; potassium carbonate; Hexamethylphosphorous triamide;
In
tetrahydrofuran; water; toluene;
1.1: Horner-Wadsworth-Emmons reaction;
DOI:10.1021/jo052035t
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: NaH / tetrahydrofuran; various solvent(s) / 20 h / Heating
2.1: K2CO3 / H2O / 3 h / 80 °C
3.1: DIBAL-H / tetrahydrofuran; toluene / 20 °C
4.1: hexamethylphosphorous triamide; CCl4 / tetrahydrofuran / 0.33 h / -78 °C
4.2: triethylamine / tetrahydrofuran / 5 h
With
tetrachloromethane; sodium hydride; diisobutylaluminium hydride; potassium carbonate; Hexamethylphosphorous triamide;
In
tetrahydrofuran; water; toluene;
2.1: Horner-Wadsworth-Emmons reaction;
DOI:10.1021/jo052035t