Cyclohexaneacetic acid,2-carboxy-2,6,6- trimethyl-,(1S,2S)-

Base Information

• Chemical Name: Cyclohexaneacetic acid,2-carboxy-2,6,6- trimethyl-,(1S,2S)-
• CAS No.: 511-74-0
• Molecular Formula: C₁₂H₂₀O₄
• Molecular Weight: 228.288
• Mol file: 511-74-0.mol

Synonyms:1,1,3r-Trimethyl-2c-carboxymethyl-3t-carboxy-cyclohexan, Driminsaeure;trans-1,3,3-Trimethyl-1-carboxy-cyclohexyl-2-essigsaeure;(1S,2S)-2-Carboxymethyl-1,3,3-trimethyl-cyclohexanecarboxylic acid;2-Carboxy-2,6,6-trimethyl-cyclohexylessigsaeure;Driminsaeure;

Chemical Property of Cyclohexaneacetic acid,2-carboxy-2,6,6- trimethyl-,(1S,2S)-

Chemical Property:

• Melting Point: 166-167 °C
• Boiling Point: 384.6±15.0 °C(Predicted)
• PSA: 74.60000
• Density: 1.098±0.06 g/cm3(Predicted)
• LogP: 2.37830

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Cyclohexaneacetic acid,2-carboxy-2,6,6- trimethyl-,(1S,2S)-

There total 6 articles about Cyclohexaneacetic acid,2-carboxy-2,6,6- trimethyl-,(1S,2S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ 1,1,3r-Trimethyl-2c-carboxymethyl-3t-carboxy-cyclohexan, Driminsaeure (511-74-0,813427-81-5)

Guidance literature:

With sodium dichromate; sulfuric acid;

DOI:10.1039/jr9590003322

Reference yield:

→ 1,1,3r-Trimethyl-2c-carboxymethyl-3t-carboxy-cyclohexan, Driminsaeure (511-74-0,813427-81-5)

Guidance literature:

Reaktion ueber mehrere Stufen;

DOI:10.1002/hlca.19560390121

Reference yield:

C30H42O3 (86699-54-9) → 1,1,3r-Trimethyl-2c-carboxymethyl-3t-carboxy-cyclohexan, Driminsaeure (511-74-0,813427-81-5)

Guidance literature:

Multi-step reaction with 2 steps

1: standing in the air

2: ozonolysis

DOI:10.1016/S0040-4039(00)81702-5

upstream raw materials:

chamaecydin

13-acetoxytotara-8,11,13-trien-7-one

C₃₀H₄₂O₃

Refernces

• 1、 Hirose, Yoshiyuki,Hasegawa, Shinichi,Ozaki, Naotake. "THREE NEW TERPENOID QUINONE METHIDES FROM THE SEED OF CHAMAECYPARIS OBTUSA". . p. 1535 - 1538. Retrieved 2007/10/02.