2-Undecanamine

Base Information

• Chemical Name: 2-Undecanamine
• CAS No.: 13205-56-6
• Deprecated CAS: 37227-98-8
• Molecular Formula: C11H25 N
• Molecular Weight: 171.326
• Hs Code.: 2921199090
• European Community (EC) Number: 236-173-6
• DSSTox Substance ID: DTXSID40884583
• Nikkaji Number: J213.748H
• Mol file: 13205-56-6.mol

Synonyms:2-Aminoundecane;2-Undecanamine;13205-56-6;undecan-2-amine;1-Methyldecylamine;2-Undecylamine;(1-methyl-decyl)-amine;EINECS 236-173-6;SCHEMBL940521;DTXSID40884583;AKOS009391762;FT-0636835;E85889

Chemical Property of 2-Undecanamine

Chemical Property:

• Vapor Pressure: 0.0631mmHg at 25°C
• Refractive Index: 1.44
• Boiling Point: 113°C/26mm
• Flash Point: 93.3°C
• PSA: 26.02000
• Density: 0.799g/cm³
• LogP: 4.17460
• XLogP3: 4.3
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 8
• Exact Mass: 171.198699802
• Heavy Atom Count: 12
• Complexity: 81.1

Purity/Quality:

98%min ^*data from raw suppliers

1-METHYLDECYLAMINE Aldrich ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCC(C)N

Technology Process of 2-Undecanamine

There total 6 articles about 2-Undecanamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

2-azidoundecane → 1-methyldecylamine (13205-56-6)

Guidance literature:

With dichloroborane-dimethyl sulfide; In dichloromethane; for 1h; Heating;

DOI:10.1016/S0040-4020(02)01322-4

Reference yield:

1,4-dioxane (123-91-1,28347-88-8,28347-91-3,39449-24-6,54841-74-6) + N-(1-methyl-decyl)-formamide (78527-33-0) → 1-methyldecylamine (13205-56-6) + methyl nonyl ketone (112-12-9)

Guidance literature:

at 185 ℃; under 84583.4 Torr; Hydrogenation;

Reference yield:

undecan-2-one oxime (2158-28-3) → 1-methyldecylamine (13205-56-6)

Guidance literature:

With ethanol; sodium; acetic acid; at 70 - 75 ℃;

upstream raw materials:

undecan-2-one oxime

methyl nonyl ketone

N-(1-methyl-decyl)-formamide

1,4-dioxane

Refernces

• 1、 Salunkhe, Ashok M.,Veeraraghavan Ramachandran,Brown, Herbert C.. "Selective reductions. Part 60: Chemoselective reduction of organyl azides with dichloroborane-dimethyl sulfide". . p. 10059 - 10064. Retrieved 2007/10/03.