trichloro(2-methylpropyl)germane

Base Information

• Chemical Name: trichloro(2-methylpropyl)germane
• CAS No.: 13892-14-3
• Molecular Formula: C4H9Cl3Ge
• Molecular Weight: 236.1133
• Mol file: 13892-14-3.mol

Synonyms:

Chemical Property of trichloro(2-methylpropyl)germane

Chemical Property:

• Vapor Pressure: 2.27mmHg at 25°C
• Boiling Point: 167.2°Cat760mmHg
• Flash Point: 45.1°C
• Density: g/cm³

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of trichloro(2-methylpropyl)germane

There total 3 articles about trichloro(2-methylpropyl)germane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 31.0%

germanium hydride trichloride (1184-65-2) + isobutene (115-11-7,15220-85-6) → (2-methylpropyl)-(1'-trichlorogermyl-2',2'-dimethyl)ethyldichlorogermane (100851-14-7) + tert-butyltrichlorogermane (1184-92-5) + 2-Methyl-1-trichlorgermyl-propan (13892-14-3)

Guidance literature:

In neat (no solvent); addn. of HGeCl3 to isobutylene with mixing in a stream of Ar, -10 - -15°C, 10 min; fractionated distn.; elem. anal.;

DOI:10.1007/BF00956097

Reference yield:

triisobutylaluminum (100-99-2,130565-62-7) + germaniumtetrachloride (10038-98-9) → 2-Methyl-1-trichlorgermyl-propan (13892-14-3)

Guidance literature:

With tributyl-amine;

Reference yield:

→ 2-Methyl-1-trichlorgermyl-propan (13892-14-3)

Guidance literature:

Cl3GeH, 2-Methyl-propen;

upstream raw materials:

triisobutylaluminum

germaniumtetrachloride

germanium hydride trichloride

isobutene

Refernces