PHTHALOCYANINE PLATINUM

Base Information

• Chemical Name: PHTHALOCYANINE PLATINUM
• CAS No.: 14075-08-2
• Molecular Formula: C32H16 N8 Pt
• Molecular Weight: 707.613
• Mol file: 14075-08-2.mol

Synonyms:Phthalocyanine,platinum deriv. (6CI); Platinum, [29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]-,(SP-4-1)-; Platinum, [phthalocyaninato(2-)]- (7CI,8CI); 29H,31H-Phthalocyanine,platinum complex; 29H,31H-Phthalocyanine, platinum deriv.;Phthalocyaninatoplatinum; Platinum phthalocyanine; Platinum(2+)phthalocyaninate; Platinum(2+) phthalocyanine; [Phthalocyaninato(2-)]platinum

Chemical Property of PHTHALOCYANINE PLATINUM

Chemical Property:

• Melting Point: >360℃
• PSA: 65.32000
• LogP: 1.46190

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of PHTHALOCYANINE PLATINUM

There total 5 articles about PHTHALOCYANINE PLATINUM which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

phthalic anhydride (85-44-9) + platinum(II) chloride (10025-65-7) → phthalocyaninato platinum(II) (14075-08-2)

Guidance literature:

With ammonium chloride; urea; ammonium molybdate; In solid; other Radiation; ligand, urea, NH4Cl, (NH4)2MoO4 and PtCl2 were finely ground, placed in beaker and irradiated in microwave oven at high power for 4 min, oven power turned to medium, 3 min; ground, washed with hot water, dried, repptd. from conc. H2SO4, soxhlet extn. for 3 h with acetone; elem. anal.;

Reference yield: 32.0%

isoindole-1,3-diylidenediamine (160956-25-2,160956-26-3,160956-27-4,160956-28-5,160956-29-6) → phthalocyaninato platinum(II) (14075-08-2)

Guidance literature:

With ammonia; platinum(II) chloride; In 2-(N,N-dimethylamino)ethanol; for 24h; Reflux;

DOI:10.1016/j.tet.2010.02.079

Reference yield: 20.0%

phthalonitrile (91-15-6) + platinum(II) chloride (10025-65-7) → phthalocyaninato platinum(II) (14075-08-2)

Guidance literature:

In neat (no solvent); PtCl2 and phthalonitrile were ground and thorougly mixed; heated at 200°C for 1 h; cooled; washed with methanol; sublimed (140°C, atm. pressure; sublimed (small batches, 550°C, 1E-3 mmHg, 8 h); elem. anal.;

DOI:10.1039/b401880j

upstream raw materials:

phthalonitrile

platinum(II) chloride

phthalic anhydride

isoindole-1,3-diylidenediamine

Refernces

• 1、 Jiang, Junhua,Kucernak, Anthony. "Electrochemistry of platinum phthalocyanine microcrystals: II. A microelectrode observation of nucleation-growth controlled solid-solid phase transformations in non-aqueous solvent". . p. 1223 - 1231. Retrieved 2001.
• 2、 Lokesh,Uma,Achar. "The Microwave-assisted syntheses and a conductivity study of a platinum phthalocyanine and its derivatives". . p. 1022 - 1028. Retrieved 2009.
• 3、 Brown, Richard J. C.,Kucernak, Anthony M.,Long, Nicholas J.,Mongay-Batalla, Carlos. "Spectroscopic and electrochemical studies on platinum and palladium phthalocyanines". . p. 676 - 680. Retrieved 2004.