N1,N1,N4,N4-Tetrakis(4-nitrophenyl)benzene-1,4-diamine

Base Information

• Chemical Name: N1,N1,N4,N4-Tetrakis(4-nitrophenyl)benzene-1,4-diamine
• CAS No.: 3283-05-4
• Molecular Formula: C30H20N6O8
• Molecular Weight: 592.524
• Hs Code.: 2921590090
• European Community (EC) Number: 608-790-4
• DSSTox Substance ID: DTXSID7062950
• Nikkaji Number: J421.665B
• Wikidata: Q72507361
• Mol file: 3283-05-4.mol

Synonyms:3283-05-4;N1,N1,N4,N4-Tetrakis(4-nitrophenyl)benzene-1,4-diamine;N,N,N',N'-Tetrakis(4-nitrophenyl)-1,4-benzenediamine;N,N,N',N'-Tetrakis(4-nitrophenyl)-p-phenylenediamine;1,4-Benzenediamine, N,N,N',N'-tetrakis(4-nitrophenyl)-;1-N,1-N,4-N,4-N-tetrakis(4-nitrophenyl)benzene-1,4-diamine;N,N,N',N'-Tetrakis(4-nitrophenyl)-1,4-phenylenediamine;N1,N1,N4,N4-Tetrakis(4-nitrophenyl)-benzene-1,4-diamine;SCHEMBL8986915;DTXSID7062950;C30H20N6O8;MFCD23135517;AKOS016005057;AS-69065;T3456;T72300;1,4-Benzenediamine, N1,N1,N4,N4-tetrakis(4-nitrophenyl)-

Chemical Property of N1,N1,N4,N4-Tetrakis(4-nitrophenyl)benzene-1,4-diamine

Chemical Property:

• Melting Point: 392°C(lit.)
• Boiling Point: 790.5°Cat760mmHg
• PKA: -9.23±0.60(Predicted)
• Flash Point: 431.9°C
• PSA: 189.76000
• Density: 1.484g/cm³
• LogP: 10.35180
• XLogP3: 7.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 10
• Rotatable Bond Count: 6
• Exact Mass: 592.13426162
• Heavy Atom Count: 44
• Complexity: 839

Purity/Quality:

98% ^*data from raw suppliers

N,N,N'',N''-Tetrakis(4-nitrophenyl)-1,4-phenylenediamine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CC=C1N(C2=CC=C(C=C2)[N+](=O)[O-])C3=CC=C(C=C3)[N+](=O)[O-])N(C4=CC=C(C=C4)[N+](=O)[O-])C5=CC=C(C=C5)[N+](=O)[O-]
• Uses: N,N,N'',N''-Tetrakis(4-nitrophenyl)-1,4-phenylenediamine is a reagent for the gelation of a highly fluorescent urea-containing triarylamine derivative N,N,N'',N''-tetrakis(p-octadecylureido-phenyl)-p-phenylenediamine in organic solvents.

Technology Process of N1,N1,N4,N4-Tetrakis(4-nitrophenyl)benzene-1,4-diamine

There total 3 articles about N1,N1,N4,N4-Tetrakis(4-nitrophenyl)benzene-1,4-diamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

4-chlorobenzonitrile (100-00-5) + 1,4-phenylenediamine (106-50-3) → N1,N1,N4,N4-tetrakis(4-nitrophenyl)-p-phenylenediamine (3283-05-4)

Guidance literature:

With potassium carbonate; copper; In 1-methyl-pyrrolidin-2-one; for 70h; Heating / reflux;

Reference yield: 96.0%

4-Fluoronitrobenzene (350-46-9,178603-76-4) + 1,4-phenylenediamine (106-50-3) → N1,N1,N4,N4-tetrakis(4-nitrophenyl)-p-phenylenediamine (3283-05-4)

Guidance literature:

With potassium carbonate; In 1-methyl-pyrrolidin-2-one; for 72h; Reflux;

DOI:10.1039/c9cc08107k

Reference yield:

→ N1,N1,N4,N4-tetrakis(4-nitrophenyl)-p-phenylenediamine (3283-05-4)

Guidance literature:

entspr. Diamin, Halogenid;

upstream raw materials:

4-chlorobenzonitrile

1,4-phenylenediamine

4-Fluoronitrobenzene

Downstream raw materials:

N¹,N¹,N⁴,N⁴-tetrakis(4-aminophenyl)-p-phenylenediamine

Refernces

• 1、 -. "Method of producing near-infrared absorbing dye compound". Page/Page column 14-15. . Retrieved 2008/06/13.